高等学校化学学报

高等学校化学学报 ›› 1999, Vol. 20 ›› Issue (10): 1656.

• 论文 • 上一篇    

氯乙烯/N-苯基马来酰亚胺共聚物的玻璃化温度研究

杜淼, 翁志学, 单国荣, 黄志明, 潘祖仁   

  1. 浙江大学高分子科学与工程研究所, 杭州 310027
  • 收稿日期:1998-12-01 出版日期:1999-10-24 发布日期:1999-10-24
  • 通讯作者: 杜淼,女,27岁,博士研究生.
  • 作者简介:杜淼,女,27岁,博士研究生.
  • 基金资助:

    教育部博士点专项科研基金(批准号:9533504)资助课题

Studies on the Glass Transition Temperature of VC/PMI Copolymer

DU Miao, WENG Zhi-Xue, SHAN Guo-Rong, HUANG Zhi-Ming, PAN Zu-Ren   

  1. Institute of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:1998-12-01 Online:1999-10-24 Published:1999-10-24

PDF (PC)

被引次数

11

摘要： 研究了单体配比、聚合温度、转化率和加料方式对氯乙烯(VC)/N-苯基马来酰亚胺(PMI)共聚物的玻璃化温度的影响.用序列模型模拟了玻璃化温度与转化率的关系,可较好地反映变化趋势.分批加料可使共聚物的耐热性能提高,却使其颗粒特性变差.

关键词: 氯乙烯, N-苯基马来酰亚胺, 共聚物, 玻璃化温度

Abstract: The effects of monomer ratio, temperature, conversion, and feeding modes on the glass transition temperature of VC/PMI copolymer were investigated on the basis of the structure and the feature of copolymerization process. The relationship between glass transition temperature and conversion was predicted by using sequence model and was nearly in agreementwith the experimental data. Portionwise feeding can improve the heat-resistant properties of the copolymer, but lead to worse particle properties.

Key words: Vinyl chloride, N-Phenyl maleimide, Copolymer, Glass transition temperature

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