高等学校化学学报

高等学校化学学报 ›› 1996, Vol. 17 ›› Issue (11): 1678.

• 论文 • 上一篇    下一篇

6,6'-二(二苯基氧化膦甲基)-1,1'-氮氧化-2,2'-联吡啶与硝酸铒配合物的合成与结构

冯银厂1, 唐瑜1, 唐宁1, 甘新民1, 谭民裕1, 郁开北2   

  1. 1. 兰州大学化学系, 兰州, 730000;
    2. 中国科学院成都分析测试中心
  • 收稿日期:1995-11-08 出版日期:1996-11-24 发布日期:1996-11-24
  • 通讯作者: 冯银厂,男,29岁,硕士.
  • 作者简介:冯银厂,男,29岁,硕士.
  • 基金资助:

    国家教委优秀年轻教师基金;甘肃省自然科学基金

Synthesis and Crystal Structure of Erbium Nitrate Complex with 6,6'-Bis(diphenylphosphine oxide methyl)-2,2'-bipyridine-1,1'-dioxide

FENG Yin-Chang1, TANG Yu1, TANG Ning1, GAN Xin-Min1, TAN Min-Yu1, YU Kai-Bei2   

  1. 1. Department of Chemistry, Lanzhou University, Lanzhou, 730000;
    2. Instrumental Analysis Center, Chengdu Institute, Chinese Academy of Sciences, Chengdu, 610015
  • Received:1995-11-08 Online:1996-11-24 Published:1996-11-24

PDF (PC)

被引次数

1

摘要： 合成了硝酸铒与四功能团含磷萃取剂6,6'-二(二苯基氧化膦甲基)-1,1'-氮氧化-2,2'-联吡啶的配合物。用四圆衍射仪测定了配合物的晶体结构。晶体属单斜晶系,空间群C2/c,晶体学参数,a=1.9830(4)nm,b=2.3135(4)nm,c=1.8600(3)nm;β=96.18(2)°,z=4.配合物中有机配体以四齿形式与中心离子铒配位,金属离子的配位数为8.配位几何构形为稍变形的四方反棱柱。金属离子周围的配位水分子已全部被取代。

关键词: 6, 6'-二(二苯基氧化膦甲基)-1, 1'-氮氧化-2, 2'-联吡啶, 硝酸铒配合物, 晶体结构

Abstract: The erbium nitrate complex with 6,6'-bis(diphenylphosphine oxide methyl)-2,2'-bipyridine-1,1'-dioxide was synthesized and characterized by IRspectra and molar conductance.The crystal and molecular structures of the complex were determined by single crystal X-ray diffraction technique with a four circle diffractometer to give final R and Rw values of 0.0541 and 0.0490.The crystal of the complex is monoclinic with a space group C2/c.The unit cell parameters are:α=1.9830(4)nm,b=2.3135(4)nm,c=1. 8600(3)nm;β=96.18(2)°,z=4,V=8.484(3)nm3,Dc=1.33g/cm3. The Er3+ ion is chelated by four P=Oand four N-O groups from the two organic ligands. All the coordinated water molecules are replaced by the organic ligands.

Key words: 6,6'-Bis(diphenylphosphine oxide methyl)-2,2'-bipyridine-1,1'-dioxide, Erbium nitrate complex, Crystal structure

TrendMD: