高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (9): 1225.

• 论文 • 上一篇    下一篇

化学法沉积银岛膜上的表面增强拉曼散射(Ⅱ)

张建华, 梁映秋   

  1. 吉林大学理论化学研究所, 长春, 130023
  • 收稿日期:1990-04-23 出版日期:1991-09-24 发布日期:1991-09-24
  • 通讯作者: 张建华
  • 基金资助:

    国家自然科学基金

Surface Enhanced Raman Scattering of Malachite Green on Silver Film From Chemical Method (Ⅱ)

Zhang Jian-hua, Liang Ying-qiu   

  1. Institute of Theoretical Chemistry, Jilin University, Changchun, 130023
  • Received:1990-04-23 Online:1991-09-24 Published:1991-09-24

PDF (PC)

被引次数

8

摘要： 用化学法在抛光的石英玻璃片上沉积银岛膜,并在该膜上进行孔雀石绿分子的表面增强拉曼散射研究,着重考察了激发波长、电解质浓度以及酸度对SERS的影响。

关键词: 表面增强拉曼散射, 孔雀石绿, 吸附

Abstract: We measured the surface enhanced Raman spectra (SERS) of the malachite green on silver film deposited on optic polished quartz slides by using chemical method. The effects of the excitation wavelength, electrolyte (NaCl) concentration and pHon the SERS were investigated. The results indicate that the relative intensities for some bands depended upon the excitation wavelength; Inorganic anion(Cl-) not only enhanced the SERSintensities, but also changed the relative intensities of the SERSsensitive bands; The SERS intensities increased with pHfrom 1-7 and reached maximum value at pH=7, and then decreased. The possible origin for the phenomena was discussed.

Key words: Surface enhanced raman scattering, Malachite green, Adsorption

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