高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (10): 1350.

• 论文 • 上一篇    下一篇

一种合成6或7位乙酰基Lumazine环系衍生物的新途径

宋艳玲   

  1. 北京大学化学系, 北京, 100871
  • 收稿日期:1990-09-20 出版日期:1991-10-24 发布日期:1991-10-24

A Novel Approach to the Synthesis of Derivative of 6-Acetyl or 7-Acetyl Lumazine Ring Systems

Song Yan-ling   

  1. Department of Chemistry, Peking University, Beijing, 100871
  • Received:1990-09-20 Online:1991-10-24 Published:1991-10-24

摘要: 标题化合物的合成目的,在于研究其结构与稳定性的关系,用其解释Vb2的生命前合成中某些反应的机理,有关此种化合物的合成文献报道甚少,而且步骤较多。

关键词: 吡嗪环, 2, 4-二氧四氢喋啶, 取代嘧啶, 2, 3, 4-戊三酮

Abstract: Six compounds containing lumazine ring were prepared by the reaction of 4,5-diamino-2,6-dihydroxy-pyrimidine and its derivative with the 2,3, 4-pentanetrione, respectively. Among them, four are new compounds. The structures of these products were proved by 1HNMR, MS spectra.

Key words: Pyrazine ring, Lumazine, Substituted pyrimidine, 2,3,4-Pentanetrione

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