高等学校化学学报

高等学校化学学报 ›› 1991, Vol. 12 ›› Issue (10): 1297.

• 论文 • 上一篇    下一篇

α-甲基丙烯酸铜(Ⅱ)与2,2'-联吡啶三元配合物的研究

王尧宇, 高忆慈, 祝英, 史启祯   

  1. 兰州大学化学系, 兰州, 730000
  • 收稿日期:1990-07-10 出版日期:1991-10-24 发布日期:1991-10-24
  • 通讯作者: 王尧宇
  • 基金资助:

    国家自然科学基金

Studies on Complex of Copper (Ⅱ) α-Methylacrylate with 2,2'-Bipyridine

Wang Yao-yu, Gao Yi-ci, Zhu Ying, Shi Qi-zhen   

  1. Department of Chemstry, Lanzhou University, Lanzhou, 730000
  • Received:1990-07-10 Online:1991-10-24 Published:1991-10-24

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摘要： Edmondson和Mrozinski分别在1965和1983年合成了不饱和烯酸铜(Ⅱ)与单齿氮配体配合物,用EPR、IR和磁化率等数据确定其组成为双核配合物,其中羧基为二齿配体,α,β-不饱和烯酸铜(Ⅱ)与二齿杂环氮形成的三元配合物迄今未见报道。

关键词: &alpha, -甲基丙烯酸铜(Ⅱ), 2, 2&prime, -联吡啶, 三元配合物

Abstract: A detailed synthesis is described for complex of copperα-methylacrylate with 2,2'-bipyridine. Elementary analysis, thermal analysis, conductivity data, susceptibility, IRand UV-vis spectra indicate the complex as [Cu(CH2=C(CH3)COO)2(bipy)(H2O)]. The molecular structure of the title compound was determined by single crystal X-ray diffraction. The crystal is a monoclinic and the lattice parameters are: α=0. 6851(1) nm, 6=1. 7626(2) nm, c=1. 5553(1) nm,β=96. 52 (1)°.

Key words: Copper α-Methylacrylate, 2,2'-Bipyridine, Ternary complex

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