高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (8): 852.

• 研究论文 • 上一篇    下一篇

聚乙烯基撑碳酸酯和聚羟基甲撑的合成与表征

黄家贤1, Adriaan Bantjes2, Leen van der Does2   

  1. 1. 南开大学化学系;
    2. 特温梯大学化工系
  • 收稿日期:1987-01-09 出版日期:1989-08-24 发布日期:1989-08-24
  • 通讯作者: 黄家贤

Synthesis and Characterization of Polyvinylene Carbonate and Polyhydroxymethylene

Huang Jiaxian1, Adriaan Bantjes2, Leen van der Does2   

  1. 1. Department of Chemistry, Nankai University, Tianjin;
    2. Department of Chemical Technology, Twente University, Netherlands
  • Received:1987-01-09 Online:1989-08-24 Published:1989-08-24

摘要: 通过乙烯基撑碳酸酯的聚合制得了无色透明的高分子量的聚合物.再经水解制得了聚羟基甲撑膜和粉状物.研究了在丙酮和二甲基甲酰胺中聚乙烯基撑碳酸酯的降解机理.

关键词: 聚乙烯基撑碳酸酯, 聚羟基甲撑, 降解

Abstract: Polymerization of vinylene carbonate gave colourless polymers with high molecular weights.Films and powders of polyhydroxymethylene were obtained by hydrolysis of polyvinylene carbonate.Mechanism of degradation of polyvinylene carbonate in acetone and DMFwas studied.

Key words: Polyvinylene carbonate, Polyhydroxymethylene, Degradation

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