高等学校化学学报

高等学校化学学报 ›› 1989, Vol. 10 ›› Issue (10): 1017.

• 研究论文 • 上一篇    下一篇

二茂铁偶姻衍生物前体——2-二茂铁基-2-(芳基羟甲基)-1,3-二噻烷的合成

孙利军, 师树简   

  1. 北京化工学院应用化学系
  • 收稿日期:1988-05-10 出版日期:1989-10-24 发布日期:1989-10-24
  • 通讯作者: 师树简
  • 基金资助:

    国家自然科学基金

Synthesis of the Precursor of Acyloin Derivatives of Ferrocene——2-Ferrocenyl-2-(Aryl Hydroxymethyl)-1,3-Dithiane

Sun Lijun, Shi Shujian   

  1. Beijing Institute of Chemical Technology, Beijing
  • Received:1988-05-10 Online:1989-10-24 Published:1989-10-24

PDF (PC)

摘要： 用2-二茂铁基-1,3-二噻烷的锂代物与芳基羰基化合物的反应,合成了16种2-二茂铁基-2-(芳基羟甲基)-1,3-二噻烷.简要讨论了产物的1HNMR谱以及羰基化合物结构对反应的影响.

关键词: 偶姻, 1, 3-二噻烷, 二茂铁衍生物

Abstract: The aim of this work is to develop a new route for the synthesis of ferrocenyl acyloin derivatives.The route consists of the reaction of 2-ferrocenyl- 1, 3-dithiane with aryl carbonyl compounds to form a class of intermediates, 2-ferrocenyl- 2- (aryl hydroxylmethyl)-l,3-dithianes(Ⅲ), which are then hydrolyzed to afford the desired products.In this paper we only report the synthesis and some properties of the intermediates (Ⅲ).Sixteen of the intermediates (Ⅲ) are obtained, they are all new ferrocene derivatives.

Key words: Acyloin, Dithiane, Ferrocene derivative

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