高等学校化学学报 ›› 1988, Vol. 9 ›› Issue (5): 504.

• 论文 • 上一篇    下一篇

Ni(Ⅱ)和Zn(Ⅱ)的乙基黄原酸盐与吡啶碱配合物的合成及性质的研究

张文昭, 戴寰, 余宝元, 张陵森   

  1. 南京大学化学系
  • 收稿日期:1986-11-05 出版日期:1988-05-24 发布日期:1988-05-24
  • 通讯作者: 张文昭

A Study of Syntheses and Properties of Ethylxanthate and Pyridine Base Complexes of Nickel and Zinc

Zhang Wenzhao, Dai Huan, Yu Baoyuan, Zhang Lingsen   

  1. Department of Chemistry, Nanjing University, Nanjing
  • Received:1986-11-05 Online:1988-05-24 Published:1988-05-24

关键词: 镍, 锌, 乙基黄原酸盐

Abstract: The mixed complexes of three nickel and two zinc xanthates with pyridine bases were synthesized and characterized by infrared spectra,thermogravimetric(TG), bifferential thermal analyses (DTA), electronic spectra and magnetic susceptibilities. The relationship between their structures and properties are also studied. The thermal stabilities of nickel (or zinc) complexes are in the order. Ni(Exan)2·2γ-pic>Ni(Exan)2·2Py>Ni(Exan)2·2P3a

Key words: Nickel, Zinc, Ethylxanthate

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