高等学校化学学报 ›› 2018, Vol. 39 ›› Issue (3): 422-426.doi: 10.7503/cjcu20170423

• 研究论文: 无机化学 • 上一篇    下一篇

六元瓜环修饰的花团状铜的催化活性

李娟, 祝林芳, 赵安婷(), 雷国明, 高丽, 夏文, 汪丽   

  1. 贵州大学化学与化工学院, 贵阳 550025
  • 收稿日期:2017-07-03 出版日期:2018-03-10 发布日期:2018-01-23
  • 作者简介:联系人简介: 赵安婷, 女, 副教授, 主要从事功能材料研究. E-mail:atzhao@sina.com
  • 基金资助:
    国家自然科学基金(批准号: 21272045)、 贵州大学大学生研究训练计划(SRT)基金[批准号: (2015)159]和国家级大学生创新训练计划项目(批准号: 201610657011)资助

Catalytic Activity of Cucurbit[6]uril Modified Copper Flower Clusters

LI Juan, ZHU Linfang, ZHAO Anting*(), LEI Guoming, GAO Li, XIA Wen, WANG Li   

  1. College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550025, China
  • Received:2017-07-03 Online:2018-03-10 Published:2018-01-23
  • Contact: ZHAO Anting E-mail:atzhao@sina.com
  • Supported by:
    † Supported by the National Natural Science Foundation of China(No.21272045), the Student Research Training(SRT) Foundation of Guizhou Universitity, China[No.(2015)159] and the National College Students’ Innovative Training Program of China(No.201610657011)

摘要:

采用水热法, 将六元瓜环(Q[6])分散的五水硫酸铜用抗坏血酸还原后获得了六元瓜环修饰的超微花团状铜(Q[6]-Cu花团). 利用X射线粉末衍射(XRD)和扫描电子显微镜(SEM)对产物进行了结构和形貌表征, 通过催化氧化染料罗丹明B(RhB)、 结晶紫(CV)、 茜素红(AR)和次甲基蓝(MB)考察了产物的催化性能. 结果表明, Q[6]-Cu花团直径约为2.0 μm. 在Q[6]-Cu/H2O2体系中, 0.08 g/L的Q[6]-Cu在300 min内对染料脱色效率均超过87%.

关键词: 六元瓜环, 花团状铜, 水热法, 染料, 催化性能

Abstract:

Cucurbit[6]uril modified copper flower clusters(Q[6]-Cu) were prepared by hydrothermal method with cucurbit[6]uril dispersed copper sulphate pentahydrate being reduced by ascorbic acid. X-Ray diffraction(XRD) and scanning electron microscopy(SEM) were used to characterize the structure and morphology of the products and the catalytic oxidation property of the product was investigated by catalytic oxidation of rhodamine B, crystal violet, alizarin red and methylene blue. The results show that the copper had special flower clusters morphology when the molar ratio of Q[6] to copper sulphate pentahydrate was 1∶25, and the average diameter of copper flower clusters was 2 μm. In the presence of Q[6]-Cu/H2O2, when the amount of copper flower clusters was 0.08 g/L and the reaction time was 300 min, the dyes decoloration efficiency was higher than 87%.

Key words: Cucurbit[6]uril, Copper flower cluster, Hydrothermal method, Dye, Catalytic property

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