碳纳米管网/聚苯胺复合材料的制备及电化学储能性能

doi:10.7503/cjcu20150579

高等学校化学学报 ›› 2016, Vol. 37 ›› Issue (1): 73.doi: 10.7503/cjcu20150579

碳纳米管网/聚苯胺复合材料的制备及电化学储能性能

江奇, 陈建康, 陈姿, 和腊梅, 卢晓英, 胡爱琳

西南交通大学超导与新能源研发中心, 材料先进技术教育部重点实验室, 成都 610031

收稿日期:2015-07-23 出版日期:2016-01-10 发布日期:2015-12-20
基金资助:
国家自然科学基金(批准号: 50907056)、四川省科技创新苗子工程项目(批准号: 2014-071)和成都市惠民科技计划项目(批准号: 2014-HM01-00073-SF)资助

Preparation and Electrochemical Energy Storage Performances of Carbon Nanotube Network/Polyaniline Composite^†

JIANG Qi^*, CHEN Jiankang, CHEN Zi, HE Lamei, LU Xiaoying, HU Ailin

Key Laboratory of Advanced Technologies of Materials, Ministry of Education, Superconductivity and New Energy Research and Development Centre, Southwest Jiaotong University, Chengdu 610031, China

Received:2015-07-23 Online:2016-01-10 Published:2015-12-20
Contact: JIANG Qi
Supported by:
† Supported by the National Natural Science Foundation of China(No.50907056), the Innovation Young Plant Project of Sichuan Province Science and Technology, China(No.2014-071) and the Huimin Project of Chengdu Science and Technology, China(No;2014-HM01-00073-SF)

摘要/Abstract

摘要：

分别采用粉末碳纳米管(CNT)和带连接点的碳纳米管网(CNTN)为模板, 通过与聚苯胺(PANI)有限域聚合得到了CNT/PANI和CNTN/PANI 2种复合材料. 采用透射电子显微镜和扫描电子显微镜对材料的形貌进行了表征, 采用氮气吸附-脱附分析研究了材料的孔结构参数, 运用双电四探针测试仪对材料的导电性能进行了测试, 利用恒流充放电、循环伏安、循环寿命及交流阻抗等电化学测试手段表征了材料的电化学储能性能. 结果表明, CNTN/PANI复合材料比CNT/PANI复合材料表现出更好的导电性能和电化学储能性能, 其放电比容量可达到143.2 F/g(有机电解液).

关键词: 碳纳米管, 碳纳米管网, 有限域聚合, 复合材料, 电化学储能性能

Abstract:

Using the carbon nanotube(CNT) powder and carbon nanotube network(CNTN) as the template, CNT/polyaniline(PANI) and CNTN/PANI composites were prepared via a PANI finite field polymerization method. The morphologies of the obtained samples were characterized by transmission electron microscope and scanning electron microscope. Nitrogen adsorption-desorption analysis was used to study the composites’ pore structure data, and the four-probe conductivity meter was also used to study the samples’ electric conductivity. The electrochemical energy storage performance of the obtained materials was characterized the cyclic voltammograms, galvanostatic charging/discharging curves, cycle life testing and electrochemical impedance spectroscopy. The results show that the obtained CNTN/PANI composite has higher electrochemical capacitance of 143.2 F/g(in organic electrolyte) and better electrical conductivity than the CNT/PANI, indicating that CNTN is more suitable to prepare composite with polymer than CNT powder since the CNTN has outstanding electrical conductivity, mechanical property and electrochemical energy storage property.

Key words: Carbon nanotube, Carbon nanotube network, Finite field polymerization, Composite, Electrochemical energy storage performance

中图分类号:

O641.1

TrendMD:

江奇, 陈建康, 陈姿, 和腊梅, 卢晓英, 胡爱琳. 碳纳米管网/聚苯胺复合材料的制备及电化学储能性能. 高等学校化学学报, 2016, 37(1): 73.

JIANG Qi, CHEN Jiankang, CHEN Zi, HE Lamei, LU Xiaoying, HU Ailin. Preparation and Electrochemical Energy Storage Performances of Carbon Nanotube Network/Polyaniline Composite^†. Chem. J. Chinese Universities, 2016, 37(1): 73.

图/表 7

Fig.1 TEM image of CNT(A), SEM image of CNTN(B), CNT/PANI(C) and CNTN/PANI(D)

Fig.2 N2 adsorption-desorption isotherms of CNT/PANI and CNTN/PANI composites(A) and pore size distribution curves calculated by DFT method(B)

Table 1 Data of the specific surface area and pore structure of the CNT/PANI and CNTN/PANI composites*

Sample	S_BET/(m²·g^-1)	V_t/(cm³·g^-1)	Average pore size/nm
CNT/PANI	374.0	0.526	5.62
CNTN/PANI	604.3	0.740	4.90

Fig.3 CV curves of the ESC made from the CNT/PANI(a) and CNTN/PANI(b) composites with a 5 mV/s scanning rate

Fig.4 Galvanostatic charging/discharging curves of the ESC made from the CNT/PANI(a) and CNTN/PANI(b) composites with a 3.4 A/g of current density

Fig.5 Cycle life curves of the ESC made from the CNT/PANI(a) and CNTN/PANI(b) composites

Fig.6 Electrochemical impedance spectroscopy of the ESC made from the CNT/PANI(a) and CNTN/PANI(b) composites

参考文献 34

[1]	Xiao X., Peng X., Jin H. Y., Li T. Q., Zhang C. C., Gao B., Hu B., Huo K. F., Zhou J., Adv. Mater., 2013, 25(36), 4954
[2]	Miller J. R., Simon P., Science,2008, 321(5889), 651—652
[3]	Miller J. R., Burke A. F., Electrochem. Soc. Interface, 2008, 17(1), 53—57
[4]	Simon P., Gogotsi Y., Nat. Mater., 2008, 7(11), 845—854
[5]	Wang G. P., Zhang L., Zhang J. J., Chem. Soc. Rev., 2012, 41(2), 797—828
[6]	Zhou W. Y., Bai X. D., Wang E. G., Xie S. S., Adv. Mater., 2009, 21(45), 4565—4583
[7]	Ajayan P.M., Zhou O. Z., Carbon Nanotubes, Springer, Heidelberg, 2001, 391—425
[8]	An K. H., Kim W. S., Park Y. S., Moon J. M., Bae D. J., Lim S. C., Lee Y. S., Lee Y. H., Adv. Func. Mater., 2001, 11(5), 387—392
[9]	Jiang Q., Liu B. C., Qu M. Z., Zhou G. M., Zhang B. L., Yu Z. L., Acta Chim. Sin., 2002, 60(8), 1539—1542
	(江奇, 刘宝春, 瞿美臻, 周固民, 张伯兰, 于作龙. 化学学报, 2002, 60(8), 1539—1542)
[10]	MacDiarmid A. G., Chiang J. C., Richter A. F., Epstein A. J., Synthetic Met., 1987, 18(1), 285—290
[11]	Fusalba F., Gouérec P., Villers D., Bélanger D., J. Electrochem. Soc., 2001, 148(1), A1—A6
[12]	Ryu K. S., Kim K. M., Park N. G., Park Y. J., Chang S. H., J. Power Sources, 2002, 103(2), 305—309
[13]	Gupta V., Miura N., Electrochim. Acta, 2006, 52(4), 1721—1726
[14]	Meng C. Z., Liu C. H., Fan S. S., Electrochem. Commun., 2009, 11(1), 186—189
[15]	Huang F., Vanhaecke E., Chen D., Catal. Today, 2010, 150(1), 71—76
[16]	Oueiny C., Berlioz S., Perrin F.X., Prog. Polym. Sci., 2013, 39(4), 707—748
[17]	Jiang Q., Zhang Q., Du B., Zhao X. F., Zhao Y., Acta Phys. Chim. Sin., 2008, 24(9), 1719—1723
	( 江奇, 张倩, 杜冰, 赵晓峰, 赵勇. 物理化学学报,2008, 24(9), 1719—1723)
[18]	Zhao X. F., Jiang Q., Guo Y. N., Zhang N., Shan C. X., Zhao Y., J. Inorg. Mater., 2010, 25(1), 91—95
	( 赵晓峰, 江奇, 郭亚楠, 张楠, 单长星, 赵勇. 无机材料学报, 2010, 25(1), 91—95)
[19]	Jiang Q., Fu G. G., Xie D. Y., Jiang S. Q., Chen Z. L., Huang B., Zhao Y., Procedia Engineering, 2012, 27, 72—76
[20]	Zhang J., Kong L.B., Wang B., Luo Y.C., Kang L., Synthetic Met., 2009, 159(3), 260—266
[21]	Sivakkumar S., Kim W. J., Choi J., MacFarlane D. R., Forsyth M., Kim D. W., J. Power Sources, 2007, 171(2), 1062—1068
[22]	Liu J. L., Sun J., Gao L., J. Phys. Chem. C, 2010, 114(46), 19614—19620
[23]	Xie D. Y., Jiang Q., Fu G. G., Ding Y., Kang X. M., Cao W., Zhao Y., Rare Metals, 2011, 30(1), 94—96
[24]	Jiang Q., Xie D. Y., Fu G. G., Huang B., Zhao X. F., Zhao Y., Mater. Sci. Forum., 2011, 687, 61—64
[25]	Wang K., Meng Q., Zhang Y., Wei Z., Miao M., Adv. Mater., 2013, 25(10), 1494—1498
[26]	Zhang H., Cao G. P., Wang W. K., Yuan K. G., Xu B., Zhang W. F., Cheng J., Yang Y. S., Electrochim. Acta, 2009, 54(4), 1153—1159
[27]	Huang B., Jiang Q., Chen H. M., He L. M., Li X. Y., Fu G. G., Zhao Y., Rare Metals, 2011, 30(1), 98—101
[28]	He L. M., Jiang Q., Chen J. K., Sun M., Yuan S., Han D. Q., Lu X. Y., Zhao Y., Mater. Lett., 2014, 134(1), 194—197
[29]	Jiang Q., Song L. J., Zhao Y., Lu X. Y., Zhu X. T., Qian L., Ren X. M., Cai Y. D., Mater. Lett., 2007, 61(13), 2749—2752
[30]	Brunauer S., Deming L. S., Deming W. E., Teller E., J. Am. Chem. Soc., 1940, 62(7), 1723—1732
[31]	Huang Z. D., Zhang B., Oh S. W., Zheng Q. B., Lin X. Y., Yousefi N., Kim J. K., J. Mater. Chem., 2012, 22(8), 3591—3599
[32]	Li Z. F., Zhang H. Y., Liu Q., Sun L. L., Stanciu L., Xie J., ACS Appl. Mater. Inter., 2013, 5(7), 2685—2691
[33]	Salvatierra R. V., Oliverira M. M., Zarbin A. J. G., Chem. Mater., 2010, 22(18), 5222—5234
[34]	Bard A.J., Faulkner L. R., Translated by Shao Y. H., Zhu G. Y., Dong X. D., Zhang B. L.,Electrochemical Methods : Fundamentals and Applications, Chemical Industry Press, Beijing, 2005, 13—25
	(邵元华, 朱果逸, 董献堆, 张柏林[译].电化学方法: 原理和应用, 北京: 化学工业出版社, 2005, 13—25)

碳纳米管网/聚苯胺复合材料的制备及电化学储能性能

Preparation and Electrochemical Energy Storage Performances of Carbon Nanotube Network/Polyaniline Composite^†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 34

相关文章 15

编辑推荐

Metrics

本文评价

[1]	赵润瑶, 纪桂鹏, 刘志敏. 吡咯氮配位单原子铜催化剂的电催化二氧化碳还原性能[J]. 高等学校化学学报, 2022, 43(7): 20220272.
[2]	于鹏东, 关兴华, 王冬冬, 辛志荣, 石强, 殷敬华. 新型光、热双响应形状记忆聚合物的制备与性能[J]. 高等学校化学学报, 2022, 43(6): 20220085.
[3]	赵盛, 霍志鹏, 钟国强, 张宏, 胡立群. 改性钆/硼/聚乙烯纳米复合材料的制备及对中子和伽马射线的屏蔽性能[J]. 高等学校化学学报, 2022, 43(6): 20220039.
[4]	赵君禹, 王春博, 王成杨, 张克, 丛冰, 杨岚, 赵晓刚, 陈春海. 导热膨胀石墨/聚醚酰亚胺复合材料的制备与性能[J]. 高等学校化学学报, 2022, 43(4): 20210800.
[5]	高京, 何文涛, 王欣欣, 向宇姝, 龙丽娟, 秦舒浩. DOPO衍生物改性碳纳米管的制备及对聚乳酸阻燃性能的影响[J]. 高等学校化学学报, 2022, 43(3): 20210670.
[6]	闫文卿, 张则尧, 李彦. 碳纳米管透明导电薄膜的可控制备[J]. 高等学校化学学报, 2022, 43(3): 20210626.
[7]	储瑶, 王烁, 张子诺, 王艺博, 蔡以兵. 铜粒子负载泡沫基相变复合材料的制备与性能[J]. 高等学校化学学报, 2022, 43(2): 20210619.
[8]	刘杰, 李金晟, 柏景森, 金钊, 葛君杰, 刘长鹏, 邢巍. 降低直接甲醇燃料电池浓差极化的含磺化碳管阻水夹层的构建[J]. 高等学校化学学报, 2022, 43(11): 20220420.
[9]	丁钦, 张梓轩, 徐培程, 李晓宇, 段莉梅, 王寅, 刘景海. Cu, Ni, Co掺杂对Fe碳纳米管的结构及电催化性能的影响[J]. 高等学校化学学报, 2022, 43(11): 20220421.
[10]	侯从聪, 王惠颖, 李婷婷, 张志明, 常春蕊, 安立宝. N-CNTs/NiCo-LDH复合材料的制备及电化学性能[J]. 高等学校化学学报, 2022, 43(10): 20220351.
[11]	许晓坚, 李博, 林猛枭, 詹硕. 多孔碳基复合膜的真空冷冻干燥制备及高效太阳能水蒸发性能[J]. 高等学校化学学报, 2022, 43(10): 20220361.
[12]	初明月, 李峰博, 高宁, 杨昕, 于婷婷, 马慧媛, 杨桂欣, 庞海军. 轮型多金属氧酸盐复合物膜的制备及在检测亚硝酸盐中的应用[J]. 高等学校化学学报, 2022, 43(1): 20210579.
[13]	李淑蓉, 王琳, 陈玉贞, 江海龙. 金属-有机框架材料在液相催化化学制氢中的研究进展[J]. 高等学校化学学报, 2022, 43(1): 20210575.
[14]	高晓乐, 王家信, 李志芳, 李艳春, 杨冬花. 复合材料NiO_x-ZSM-5的制备及微生物电解池催化析氢性能[J]. 高等学校化学学报, 2021, 42(9): 2886.
[15]	李占峰, 刘本学, 刘晓婵, 王新强, 张晶, 于诗摩, 赵新富, 张新恩, 伊希斌. 氧化锆湿凝胶中乙酰丙酮配体的脱除机理及气凝胶复合材料的制备[J]. 高等学校化学学报, 2021, 42(9): 2904.

碳纳米管网/聚苯胺复合材料的制备及电化学储能性能

Preparation and Electrochemical Energy Storage Performances of Carbon Nanotube Network/Polyaniline Composite†

RichHTML

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

图/表 7

参考文献 34

相关文章 15

编辑推荐

Metrics

本文评价

Preparation and Electrochemical Energy Storage Performances of Carbon Nanotube Network/Polyaniline Composite^†