Chem. J. Chinese Universities

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Patterned SERS Active Substrate Fabricated by Dewetting of Silver Nanoparticles Solution

SONG Wei, ZHU Di-Fu, LI Zhi-Shi, LIU Hui-Hui, YANG Bai, ZHAO Bing*   

  1. State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012, China
  • Received:2007-06-27 Revised:1900-01-01 Online:2008-02-10 Published:2008-02-10
  • Contact: ZHAO Bing

Abstract: We present a simple and controlled method for direct fabrication of ordered 2D arrays of Surface-enhance Raman scattering(SERS) rings and disks substrate. Silver rings and disks are fabricated on patterned self-assembled monolayers on Au substrate by dewetting the solution of CTAB-coated silver nanoparticles in CHCl3. It is found that two different silver patterns assemblies are formed when the concentration of the silver nanoparticles in CHCl3 solution changes. We characterized the formation and structure of these two different silver patterns assemblies using contact mode atomic force microscopy. Surface enhanced Raman mapping of 4-MPY SAM on this novel SERS active substrate are also investigated.

Key words: Dewetting, Pattern, Ag nanopartile, Surface-enhance Raman scattering(SERS), Raman mapping

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