Crystal Structure and Mechanism of (Z)-1-[2-(Phenyl-bromide-chloride) vinyl]-1-cyclohexanol

Abstract

Abstract: The crystal structure and mechanism of the title molecule are discribed. Thiscrystal is orthorhombic, belonging to space group PC₂₁/Bwith α=1. 0021 (2) nm, b=1. 4830(3) nm, c=2. 1736(4) nm, V=3. 23039(2) nm₃, Z=2, D_c=1.80 g/cm³, R=0. 0693. The structure was solved by direct method. The tin atom of the title compoundexists in two distorted-trigonal-bipyramidal geometry, defined by two carbon, one bromide,one chloride and one oxygen atoms leading to a five-membered chelate ring. In the structure,the five-membered ring containing the intermolecular O→Sn has a half chair conformation.

Key words: (Z)-1-[2-(Phenyl-bromide-chloride)vinyl]-1-cyclohexanol, Crystal structure, Antitumor activity

CLC Number:

O627.42

TrendMD:

ZHU Dong-Sheng, DAI Hui-Cong, FU Yu-Jie, SHAN Xi-Lin, FU Fang-Xin, XING Yan, LIN Yong-Hua. Crystal Structure and Mechanism of (Z)-1-[2-(Phenyl-bromide-chloride) vinyl]-1-cyclohexanol[J]. Chem. J. Chinese Universities, 1997, 18(10): 1654.

References

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