Synthesis, Structure and Properties of a Novel Lanthanide Metal-organic Coordination Polymer with Three-dimensional Open Framework, Tm(BTC)(DMF)(DMSO)

Chem. J. Chinese Universities

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Synthesis, Structure and Properties of a Novel Lanthanide Metal-organic Coordination Polymer with Three-dimensional Open Framework, Tm(BTC)(DMF)(DMSO)

NA Li-Yan^1,2, JIANG Hui-Ming², YANG Bao-Ling², HAI Hua², NING Gui-Ling¹*

1. School of Chemical Engineering, Dalian University of Technology, Dalian 116022, China;
2. College of Life Science, Dalian Nationalities University, Dalian 116600, China

Received:2006-10-23 Revised:1900-01-01 Online:2007-08-10 Published:2007-08-10
Contact: NING Gui-Ling

Abstract

Abstract: A three-dimensional(3D) lanthanide metal-organic coordination polymer with a three-dimensional open framework, Tm(BTC)(DMF)(DMSO), was synthesized by reaction of the lanthanide ions(Tm³⁺) with 1,3,5-benzenetricarboxylic acid(H₃BTC) in a mixed solution of DMF(N,N'-dimethylformamide) and DMSO(dimethyl sulphoxide). This compound crystallizes in a monoclinic space group P2₁/n with unit cell parameters a=1.0801(2) nm, b=1.5550(3) nm, c=1.0906(2) nm, β=100.401°, V=1.8017(6) nm³ and Z=4. The compound exhibits one-dimensional channels along the [100] direction and could uptake carbon dioxide at 1×10⁵ Pa.

Key words: Metal-organic coordination polymer, Lanthanide element, Crystal structure, Adsorption

CLC Number:

O614

TrendMD:

NA Li-Yan^1,2, JIANG Hui-Ming², YANG Bao-Ling², HAI Hua², NING Gui-Ling¹*
. Synthesis, Structure and Properties of a Novel Lanthanide Metal-organic Coordination Polymer with Three-dimensional Open Framework, Tm(BTC)(DMF)(DMSO)[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Structure and Properties of a Novel Lanthanide Metal-organic Coordination Polymer with Three-dimensional Open Framework, Tm(BTC)(DMF)(DMSO)

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