Thc Crystal Structure and Electrocatalysis of Supermolecular Compound C6H20N2O64P2Mo18·8H2O

Abstract

Abstract: Anovel compound formulated [NH₂(CH₂)₄CHNH₂COOH]H₆P₂Mo₁₈O₆₂has been synthesized and its structure has been characterized, which is the first example of aminoacid-heteropolyacid species.Crystal system is orthorhombic, space group P2₁2₁2, unit cell dimensions: α=1.5722(3) nm, b=2.1181 (4) nm, c=1.2383(3) nm, α=90.04(3)°, β=90.00 (2)°, γ= 89.99 (3)°, V= 4.1236(14) nm³, Z=2, D0=2.437×10³kg/m³, R=0.0387.Experimental result shows that the title compound has electrocatalysis reactivity.

Key words: Supermolecular compound, Crystal structure, Eletrocatalysis

CLC Number:

O614.61

TrendMD:

LIU Jing-Hua, XIN Ming-Hong, WANG En-Bo, PENG Jun, BI Li-Hua. Thc Crystal Structure and Electrocatalysis of Supermolecular Compound C₆H₂₀N₂O₆₄P₂Mo₁₈·8H₂O[J]. Chem. J. Chinese Universities, 1999, 20(9): 1343.

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Thc Crystal Structure and Electrocatalysis of Supermolecular Compound C₆H₂₀N₂O₆₄P₂Mo₁₈·8H₂O

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