Synthesis and Structure of Dinuclear Copper(Ê) Complex with Nitronyl Nitroxide Biradical [Cu(hfac)2]2PhBNOM

Chem. J. Chinese Universities ›› 2000, Vol. 21 ›› Issue (3): 347.

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Synthesis and Structure of Dinuclear Copper(Ê) Complex with Nitronyl Nitroxide Biradical [Cu(hfac)₂]₂PhBNOM

ZHAO Qi-Hua¹, LIAO Dai-Zheng¹, JIANG Zong-Hui¹, YAN Shi-Ping¹, FANG Rui-Bin², ZHU Hong-Ping³

1. Department of Chemistry, Nankai University, Tianjin 300071, China;
2. Department of Chemistry, Yunnan University, Kunming 650091, China;
3. Fujian Instituteof Researchonthe Structure of Matter, Chinese Academyof Sciences, Fuzhou 350002, China

Received:1999-09-09 Online:2000-03-24 Published:2000-03-24

Abstract

Abstract: Dinuclear copper complex with biradical, [Cu(hfac)₂]₂PhBNOM[PhBNOM=2,5-bimethoxyl-1,4-bis(4,4,5,5-tetramethyllimidazoline-1-oxyl-3-oxide)phenyl, hfac=hexafluoroacetylacetonate], has been synthesized and characterized. It crystallized in the monoclinic system; space group C2/c with a = 1.8773(8) nm, b =1.3598(5) nm, c =2.2371(7) nm, β =97.24(3)°, Z =4, R = 0.0961 , R_w=00944 .

Key words: Nitronyl nitroxide biradical, Copper(Ê, ) complex, Crystal structure

CLC Number:

O614.12

TrendMD:

ZHAO Qi-Hua, LIAO Dai-Zheng, JIANG Zong-Hui, YAN Shi-Ping, FANG Rui-Bin, ZHU Hong-Ping. Synthesis and Structure of Dinuclear Copper(Ê) Complex with Nitronyl Nitroxide Biradical [Cu(hfac)₂]₂PhBNOM[J]. Chem. J. Chinese Universities, 2000, 21(3): 347.

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Synthesis and Structure of Dinuclear Copper(Ê) Complex with Nitronyl Nitroxide Biradical [Cu(hfac)₂]₂PhBNOM

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