Catalytic Performances of Co-Pd/TiO2 Catalysts Prepared with Mixed Cobalt Salts for Acetic Acid Synthesis from CH4 and CO2 by a Step-wise Reaction Sequence

doi:10.3969/j.issn.0251-0790.2012.01.027

Abstract

Abstract: Co-Pd/TiO₂ catalysts were prepared from mixed cobalt salts by incipient impregnation method. The catalytic performance of the catalysts for direct synthesis of acetic acid from CH₄ and CO₂ by a step-wise reaction technology was investigated. These catalysts were also characterized by XRD, XPS, NH₃-TPD and BET. The results show that when the precursor is from mixed cobalt salts, a suitable surface acidity, high specific surface area and pore structure are formed, which favors the activity of catalysts. On the condition of m(CoCl₂)∶m=2∶5, m(Co)∶m(Pd)=2∶1 and 150 ℃, the formation rate and selectivity of acetic acid reach 6.13 mg·g^-1Cat·h^-1and 81.6%, respectively. Compared with the catalysts prepared from single cobalt, the rate and selectivity increase by 134% and 16%.

Key words: Mixed cobalt salts, Co-Pd/TiO₂ catalyst, CH₄-CO₂ step-wise reaction, Acetic acid

CLC Number:

O643

TrendMD:

GAO Zhong-Liang, HUANG Wei, YIN Li-Hua, JI Peng, ZHAO Jin-Zhen, LIU Yuan, PENG Fen. Catalytic Performances of Co-Pd/TiO₂ Catalysts Prepared with Mixed Cobalt Salts for Acetic Acid Synthesis from CH₄ and CO₂ by a Step-wise Reaction Sequence[J]. Chem. J. Chinese Universities, 2012, 33(01): 158.

References

[1] WANG Xin-Ping(王新平), FANG Ke-Gong(房克功), CAI Tian-Xi(蔡天锡). Petrochemical Technology & Application(石化技术与应用)[J], 2001, 19(6): 351-355 [2] GE Xin(葛欣), SHEN Jian-Yi(沈俭一). Chemical Engineering of Oil & Gas(石油与天然气化工)[J], 2000, 29(6): 273-275 [3] WANG Yu-He(王玉和), HE De-Hua(贺德华), XU Bo-Qing(徐柏庆). Progress in Chemistry(化学进展)[J], 2003, 15(3): 215-221 [4] Spivey J. J.. Method of Preparing Alkyl Carboxylation of Lower Alakanes Methane, US WO99/59952, 1999-11-25 [5] ZHU Zhi-Hua(朱志华), XU Zheng-Yong(徐争勇), YU Shai-Cheng(于筛成), HE Chong-Heng(赫崇衡), XU Pei-Ruo(徐佩若). Journal of East China University of Science and Technology, Natural Science Edition(华东理工大学学报, 自然科学版))[J], 2005, 31(1): 35-38 [6] Song H., Mirkelamoglu B., Ozkan U. S.. Appl. Catal. A: Gen.[J], 2010, 382: 58-64 [7] Yang Q. J., Choi H., Chen Y. J., Dionysiou D. D.. Appl. Catal. B: Environmental[J], 2008, 77: 300-307 [8] Bae J. W., Kim S. M., Kang S. H., Chary K. V. R., Lee Y. J., Kim H. J., Jun K. W.. Journal of Molecular Catalysis A: Chemical[J], 2009, 311: 7-16 [9] Sun S. L., Tsubaki N., Fujimoto K.. Appl. Catal. A: Gen.[J], 2000, 202: 121-131 [10] Huang W., Xie K. C., Wang J. P., Gao Z. H., Yin L. H., Zhu Q. M.. J. Catal.[J], 2001, 201: 100-104 [11] ZHANG Ri-Guang(章日光), HUANG Wei(黄伟), WANG Bao-Jun(王宝俊). Chinese Journal of Catalysis(催化学报)[J], 2007, 28(7): 641-645 [12] ZHANG Ri-Guang(章日光), HUANG Wei(黄伟), WANG Bao-Jun(王宝俊). Chinese Journal of Catalysis(催化学报)[J], 2008, 29(9): 913-920 [13] XIE Ke-Chang(谢克昌), HUANG Wei(黄伟), WANG Xiao-Hong(王晓红). Chinese Journal of Catalysis(催化学报)[J], 2003, 24(3): 213-218 [14] ZHANG Shao-Hong(张韶红), HUANG Wei(黄伟). Natural Gas Chemical Industry(天然气化工)[J], 2005, 30(2): 44-48 [15] ZHAO Ting-Dong(赵庭栋). Study on Catalysts of Directly Synthesis of Acetic Acid from CH₄ and CO₂ by Two Step(CH₄-CO₂两步反应直接合成乙酸催化剂研究), Taiyuan: Taiyuan University of Technology, 2006 [16] LI Zhi-Qin(李志勤), HUANG Wei(黄伟). Journal of Molecular Catalysis(China)(分子催化)[J], 2007, 21(Suppl.): 433-434 [17] WANG Zheng-Xiang(汪正祥), HUANG Wei(黄伟), HUANG Ying(黄颖), YIN Li-Hua(阴丽华). Coal Conversion(煤炭转化)[J], 2010, 33(4): 66-69 [18] PEI Hong-Hong(裴红红), HUANG Wei(黄伟), HUANG Ying(黄颖), PENG Fen(彭芬). Applied Chemical Industry(应用化工)[J], 2010, 39(9): 1285-1288 [19] ZHAO Ming(赵明), WANG Hai-Rong(王海容), CAI Li(蔡黎), ZHU Yi(朱艺), GONG Mao-Chu(龚茂初), CHEN Yao-Qiang(陈耀强). Rare Metal Materials and Engineering(稀有金属材料与工程)[J], 2010, 39(3): 519-522 [20] WANG Yan-Hua(王艳华), ZHANG Jing-Chang(张敬畅), XU Heng-Yong(徐恒泳), BAI Xue-Feng(白雪峰). Chinese Journal of Catalysis(催化学报)[J], 2007, 28(3): 234-238 [21] DAI Xiao-Ping(代小平), YU Chang-Chun(余长春), SHEN Shi-Kong(沈师孔). Chinese Journal of Catalysis(催化学报)[J], 2000, 21(2): 161-164 [22] Zavyalova U., Scholz P., Ondruschka B.. Appl. Catal. A: Gen.[J], 2007, 323: 226-233 [23] DAI Xiao-Ping(代小平), YU Chang-Chun(余长春), LI Ran-Jia(李然家). Chinese Journal of Catalysis(催化学报)[J], 2007, 28(12): 1047-1052 [24] WU Song(吴嵩), LIU Bin-Hong(刘宾虹), YANG Jun-Qiang(杨俊强), LIU Fu(刘芙). Journal of Materials Science & Engineering(材料科学与工程学报)[J], 2010, 28(2): 189-193 [25] YANG Guo-Kai(杨国凯), DING Ke-Qiang(丁克强). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(5): 994-997 [26] YANG Gai-Xiu(杨改秀), DENG Ling-Juan(邓玲娟), TANG Ya-Wen(唐亚文), LU Tian-Hong(陆天虹). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 30(6): 1173-1176 [27] LINGMU Jun-Lang, JICHUAN Yu-Zi, ANBU Jian-Yi, ZUOYE Jian-Yi. Preparation of Acetic Acid, WO 94/22803, 1994-10-13 [28] Brik Y., Kacimi M., Ziyad M., Bozon-Verduraz F.. J. Catal.[J], 2001, 202: 118-128 [29] Chai J. W., Pan J. S., Wang S. J., Huan C. H. A., Lau G. S., Zheng Y. B., Xu S.. Surface Science[J], 2005, 589: 32-41 [30] Zsoldos Z., Guczi L.. J. Phys. Chem.[J], 1992, 96: 9393-9400 [31] Mathew T., Shiju N. R., Sreekumar K., Rao B. S., Gopinath C. S.. J. Catal.[J], 2002, 210: 405-417 [32] ZHENG Chun-Zhi(郑纯智), ZHANG Guo-Hua(张国华), WEN Ying-Pin(文颖频), ZHANG Chun-Yong(张春勇). Journal of Chemical Engineering of Chinese Universities(高校化学工程学报)[J], 2010, 24(2): 358-363 [33] Vincent Crist B.. Handbook of Monochromatic XPS Spectra[M], California: XPS International Inc., 1999 [34] Liao M. S., Zhang Q. E.. J. Mol. Catal.[J], 1998, 136: 185-194 [35] HUANG Wei(黄伟). Study on the Direct Conversion of CH₄ and CO₂ to Acetic Acid from by Two Step Reaction Sequence(CH₄-CO₂两步反应直接合成乙酸研究), Taiyuan: Taiyuan University of Technology, 2003 [36] YANG Xi-Yao(杨锡尧). Petrochemical Technology(石油化工)[J], 2001, 30(12): 952-959 [37] HUANG Ke-Long(黄可龙), LIU Ren-Sheng(刘人生), YANG You-Ping(杨幼平), LIU Su-Qin(刘素琴), WANG Li-Ping(王丽平). Acta Phys. Chim. Sin.(物理化学学报)[J], 2007, 23(5): 655-658

Catalytic Performances of Co-Pd/TiO₂ Catalysts Prepared with Mixed Cobalt Salts for Acetic Acid Synthesis from CH₄ and CO₂ by a Step-wise Reaction Sequence

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	ZHONG Shengguang, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Theoretical Study on Direct Conversion of CH₄ and CO₂ into Acetic Acid over MCu₂O_x（M = Cu²⁺， Ce⁴⁺， Zr⁴⁺） Clusters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2878.
[2]	WANG Xiaoqun, HUANG Guangming. Investigation of Lipid Distributions by Trifluoroacetic Acid-enhanced Desorption Electrospray Ionization Mass Spectrometry Imaging [J]. Chem. J. Chinese Universities, 2020, 41(12): 2673.
[3]	DONG Deming,ZHANG Ying,HUA Xiuyi,JIANG Xu,LIANG Dapeng,GUO Zhiyong. Effect of Dissolved Organic Matter on the Generation of H₂O₂ in Natural Biofilm Systems Under Illumination^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 800.
[4]	LI Bing,WANG Xuemin,BAI Fengying,LIU Shuqing. Synthesises, Structures and Antibacterial Activities of a Series of Rare Earth Nitrogen Heterocyclic Complexes^† [J]. Chem. J. Chinese Universities, 2019, 40(4): 632.
[5]	A Shan, ZHEN Jiawei, LIU Juming, BAI Jie, YANG Jucai, ZHANG Qiancheng. Preparation and Synergistic Catalytic Performance of Ag/TiO₂ Composite Photocatalysts Modified by Acetic Acid [J]. Chem. J. Chinese Universities, 2017, 38(8): 1450.
[6]	BU Huijuan, ZHANG Jing, MU Boshuai, LI Yuan. Mannich Reaction of Aromatic Ketones Based on Acetic Acid as Solvent and Catalyst^† [J]. Chem. J. Chinese Universities, 2014, 35(9): 1912.
[7]	LIN Hai-Bin, ZHENG Lin, LIN Yu-Qin, ZHOU Zhao-Hui. Study of Interaction Between Bovine Serum Albumin and Cobalt Complexes of Phenanthroline and Nitrilotriacetate by Fluorescence Spectrometry [J]. Chem. J. Chinese Universities, 2013, 34(8): 1818.
[8]	DONG Jia-Bin, WU Jian-Bo, YANG Jing, SONG Wei, DAI Xiao-Jun, YE Zheng-De, GONG Bo-Lin. Preparation of High-capacity IDA Chelating Resin and Its Adsorption Properties [J]. Chem. J. Chinese Universities, 2013, 34(3): 714.
[9]	GAO Chao, YANG Yu-Zhu, ZHANG Guang-Bo, PENG Jing-Dong, TANG Qian, GONG Cheng-Bin. Preparation and Characterization of Photoresponsive Organic-inorganic Hybrid Molecularly Imprinted Polymers [J]. Chem. J. Chinese Universities, 2012, 33(12): 2801.
[10]	WANG Qin-Hui, WANG Chao-Zhan, WEI Yin-Mao. Preparation and Adsorption Properties of New Chelating Resin Based on Chloromethylated Polystyrene Beads via Surface-initiated Atom Transfer Radical Polymerization [J]. Chem. J. Chinese Universities, 2012, 33(11): 2579.
[11]	WANG Wen-Jia, GUO Xiao-Lin, WEI An-Hui, FU Chang-Hao, HAN Zhen-Guo. Purification of Histidine-tagged Fusion Proteins Based on Fe₃O₄@SiO₂/Ni-NTA Magnetic Spheres [J]. Chem. J. Chinese Universities, 2012, 33(02): 303.
[12]	TANG Zhan, ZHANG Guo-Tao, ZHANG Tong-Lai*, LI Zhi-Min, YANG Li, ZHANG Jian-Guo, QIAO Xiao-Jing. Crystal Structure, Thermal Properties, Sensitivity Test and Catalytic Activity of Energetic Compound[Cu(tza)₂]_n [J]. Chem. J. Chinese Universities, 2011, 32(8): 1870.
[13]	XIE Guo-Fang, LU Tian-Hong, YANG Gai-Xiu, CHEN Yu, ZHOU Yi-Ming, TANG Ya-Wen*. Preparation and Mechanism of Carbon Supported Pt Catalyst Using Pt(NO3)2 and Ethylenediaminetetraacetic Acid [J]. Chem. J. Chinese Universities, 2011, 32(6): 1373.
[14]	JIN Feng-Ying, GUO Xin-Wen, WANG Xiang-Sheng*. Influence of Ethylenediamine Tetraacetic Acid on the Hydrodesulfurization Activity of Nano HZSM-5 Supported NiMo Catalyst [J]. Chem. J. Chinese Universities, 2011, 32(1): 113.
[15]	LI Yang, ZHANG Zhi-Guo, CHI Hui-Wei, LUO Yan-Mei, LIU Chang-Ling, .... Synthesis and Bioactivity of 2-Aceto-cyanoacetic Acid Derivatives [J]. Chem. J. Chinese Universities, 2010, 31(9): 1798.