Antioxidant Property of Catalyzed Lignosulfonate Using S2O82-/ZrO2 Doped Cerium as Catalysts†

doi:10.7503/cjcu20170746

Abstract

Abstract:

To improve catalysis activity of S₂ $O 8 2 -$ /ZrO₂ for the hydrogenation of lignosulfonate, rare earth cerium was doped onto the catalysts. Through Hammett indicator method and the determination of X-ray small diffraction(XRD), specific surface area(S_BET) and sulfur content, the influence of different Cerium doping ratio on the acid strength of solid acid, carrier crystal type and S_BET were discussed. Doping cerium promoted to form amorphous ZrO₂ crystal, contributed to increasing S_BET and sulfur content for solid acid enhancement. The contents of phenol hydroxyl and total hydroxyl were considered as a fractions of active groups in lignin, increased from 1.52% and 2.31% to 3.35% and 10.35%, combined with the data of ¹H nuclear magnetic spectra(¹H NMR). The results proved that the cerium doping improved S₂ $O 8 2 -$ /ZrO₂ catalytic properties through increasing the hydroxyl groups content of lignosulfonate. It confirmed that the catalyst coping Cerium was an excellent catalyst for hydrogenation of lignosulfonate dispersing in water. And hydroxylated ligno-sulfonate has good antioxidant capacity.

Key words: Coping cerium, Rare Earth solid acid, Lignonsulfonate, Antioxidant

CLC Number:

TrendMD:

ZHANG Yan, ZHANG Shengming, FANG Guizhen. Antioxidant Property of Catalyzed Lignosulfonate Using S₂ $O 8 2 -$ /ZrO₂ Doped Cerium as Catalysts^†[J]. Chem. J. Chinese Universities, 2018, 39(6): 1255.

Figures/Tables 7

References 24

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Sample	Proportion of coping cedium(%)	Calcination temperature/℃	Hammett acidity function	S_BET/(m²·g^-1)	Sulfer content(%)
ZC0	0	600	-12.70	36.2742	3.87
ZC1-1	1	550	-12.70	50.7799	5.11
ZC1-2	1	600	-12.70	52.1891	5.12
ZC1-3	1	650	-12.70	51.2678	5.12
ZC2	2	600	-12.70	51.5304	5.09
ZC3	3	600	-12.70	51.4652	5.11

Sample	Proportion of coping cedium(%)	Calcination temperature/℃	Hammett acidity function	S_BET/(m²·g^-1)	Sulfer content(%)
ZC0	0	600	-12.70	36.2742	3.87
ZC1-1	1	550	-12.70	50.7799	5.11
ZC1-2	1	600	-12.70	52.1891	5.12
ZC1-3	1	650	-12.70	51.2678	5.12
ZC2	2	600	-12.70	51.5304	5.09
ZC3	3	600	-12.70	51.4652	5.11

Sample	Proportion of catalyst(%)	Content of hydroxyl groups(%)
Sample	Proportion of catalyst(%)	Total hydroxyl group	Phenolic hydroxyl group	Alcohol hydroxyl group
LS_ZC0	10	3.28	1.70	1.58
LS_ZC1-1	5	5.03	3.00	2.03
LS_ZC1-2	7	6.12	2.13	3.99
LS_ZC1-3	10	10.79	7.34	3.45
LS_ZC2	10	8.66	5.62	3.04
LS_ZC3	10	6.28	2.03	4.25

Sample	Proportion of catalyst(%)	Content of hydroxyl groups(%)
Sample	Proportion of catalyst(%)	Total hydroxyl group	Phenolic hydroxyl group	Alcohol hydroxyl group
LS_ZC0	10	3.28	1.70	1.58
LS_ZC1-1	5	5.03	3.00	2.03
LS_ZC1-2	7	6.12	2.13	3.99
LS_ZC1-3	10	10.79	7.34	3.45
LS_ZC2	10	8.66	5.62	3.04
LS_ZC3	10	6.28	2.03	4.25

Sample	IC₅₀/(mg·mL^-1)		Sample	IC₅₀/(mg·mL^-1)
Sample	DPPH·	ABTS·	Sample	DPPH·	ABTS·
BHT	0.0316	0.0497	LS_ZC1	0.0412	0.1002
LS	0.1498	0.1499	LS_ZC2	0.0457	0.0998
LS_ZC0	0.1266	0.1094

Antioxidant Property of Catalyzed Lignosulfonate Using S₂ $O 8 2 -$ /ZrO₂ Doped Cerium as Catalysts^†

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