Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (2): 310.doi: 10.7503/cjcu20170349
• Physical Chemistry • Previous Articles Next Articles
ZHANG Baohai1, LUO Min1,*(), YANG Shun1, FU Rongrong1, MA Jinfu2
Received:
2017-06-06
Online:
2018-02-10
Published:
2017-12-05
Contact:
LUO Min
E-mail:martinluomin@163.com
Supported by:
CLC Number:
TrendMD:
ZHANG Baohai, LUO Min, YANG Shun, FU Rongrong, MA Jinfu. Preparation and Electrochemical Properties of Hierarchically Porous Carbon Microspheres Derived from Metal Phenolic Precursor†[J]. Chem. J. Chinese Universities, 2018, 39(2): 310.
Fig.4 FTTR spectra of the EA(a), ZnEA(b) and C-ZnEA-1000(c) samples(A) and XRD pattern of ZnEA(B) Inset of (B) shows the perspective view of the ZnEA molecular structure.
Fig.8 N2 adsorption-desorption isotherms(A) and the pore size distribution curves(B) of the C-ZnEA-700/800/900/1000 hierarchically porous carbon microsphere samples
Sample | BET surface area/(m2·g-1) | Porevolum/(m3·g-1) | Average pore width/nm |
---|---|---|---|
ZnEA | 5.32 | 0.02 | 14.04 |
C-ZnEA-700 | 20.25 | 0.05 | 9.69 |
C-ZnEA-800 | 95.40 | 0.12 | 5.11 |
C-ZnEA-900 | 887.29 | 0.56 | 2.55 |
C-ZnEA-1000 | 1238.13 | 0.78 | 2.52 |
Table 1 Porosity and properties of C-ZnEA-700/800/900/1000 porous carbon microsphere samples
Sample | BET surface area/(m2·g-1) | Porevolum/(m3·g-1) | Average pore width/nm |
---|---|---|---|
ZnEA | 5.32 | 0.02 | 14.04 |
C-ZnEA-700 | 20.25 | 0.05 | 9.69 |
C-ZnEA-800 | 95.40 | 0.12 | 5.11 |
C-ZnEA-900 | 887.29 | 0.56 | 2.55 |
C-ZnEA-1000 | 1238.13 | 0.78 | 2.52 |
Fig.9 Electrochemical performance of C-ZnEA-700/800/900/1000 samples(A) Cyclic voltammograms curves at a scan rate of 5 mV/s; (B) the specific capacitance variations at different scan rates.
Fig.10 Glavanostatic charge-discharge curves of C-ZnEA-1000 at different current density and specific capacitance variation and IR drop of C-ZnEA-1000 with discharge current density(B)
Fig.12 Cycle performance and Coulombic efficiency of C-ZnEA-1000(A) at 1 A/g and constant current charge-discharge curve of the Its cycle and 5000th cycle(B) The inset is the constant current charge-discharge diagram for the last 20 cycles of the cycle.
Material | Electrolyte(potential window/V) | Rate capability(%) (scan rate or current density) | Capacitance/(F·g-1)(scan rate or current density) | Cycle life(%) (Cycling No.) | Ref. |
---|---|---|---|---|---|
Zn-bdc derived porous carbon | 6 mol/L KOH (-1—0) | 65(1—100 mV/s) | 170 (1 mV/s) | 98(5000) | [ |
MOF-5 derived 3D porous carbon | 6 mol/L KOH (-0.9—0.1) | 82.9(0.05—20 A/g) | 212(0.05 A/g) | 95.9(1000) | [ |
Al-PCP derived carbons | 30% KOH (-1—0) | 75(0.1—1 A/g) | 232.8(0.1 A/g) | [ | |
ZIF-8 derived porous carbon | 1 mol/L H2SO4 (0—0.6) | 60(5—200 mV/s) | 251(15 mV/s) | 92(2000) | [ |
HPC microsphere derived from ZnEA | 6 mol/L KOH (-1.1—-0.1) | 84.67(5—100 mV/s) | 216(5 mV/s) | 97(5000) | This work |
Table 2 Comparison of capacitance of MOFs derived porous carbon supercapacitor*
Material | Electrolyte(potential window/V) | Rate capability(%) (scan rate or current density) | Capacitance/(F·g-1)(scan rate or current density) | Cycle life(%) (Cycling No.) | Ref. |
---|---|---|---|---|---|
Zn-bdc derived porous carbon | 6 mol/L KOH (-1—0) | 65(1—100 mV/s) | 170 (1 mV/s) | 98(5000) | [ |
MOF-5 derived 3D porous carbon | 6 mol/L KOH (-0.9—0.1) | 82.9(0.05—20 A/g) | 212(0.05 A/g) | 95.9(1000) | [ |
Al-PCP derived carbons | 30% KOH (-1—0) | 75(0.1—1 A/g) | 232.8(0.1 A/g) | [ | |
ZIF-8 derived porous carbon | 1 mol/L H2SO4 (0—0.6) | 60(5—200 mV/s) | 251(15 mV/s) | 92(2000) | [ |
HPC microsphere derived from ZnEA | 6 mol/L KOH (-1.1—-0.1) | 84.67(5—100 mV/s) | 216(5 mV/s) | 97(5000) | This work |
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