Chem. J. Chinese Universities ›› 2018, Vol. 39 ›› Issue (3): 530.doi: 10.7503/cjcu20170343
• Physical Chemistry • Previous Articles Next Articles
WANG Fengmei, XU Guangwei, JIN Chengchang*()
Received:
2017-06-05
Online:
2018-03-10
Published:
2018-01-13
Contact:
JIN Chengchang
E-mail:jinchengchang@suda.edu.cn
CLC Number:
TrendMD:
WANG Fengmei, XU Guangwei, JIN Chengchang. Synthesis and Electrochemical Performance for Supercapacitors of Bi-doped α-MnO2 Nanorods[J]. Chem. J. Chinese Universities, 2018, 39(3): 530.
Fig.1 X-Ray diffraction patterns of samples(A) and magnified X-ray diffraction patterns of samples between the ranges of 2θ=25°—35°(B)a. MO; b. BMO-50; c. BMO-30; d. BMO-20.
Sample | a/nm | c/nm | c/a | V/nm3 |
---|---|---|---|---|
MO | 0.98723 | 0.28707 | 0.2908 | 0.27981 |
BMO-50 | 0.98742 | 0.28689 | 0.2905 | 0.28021 |
BMO-30 | 0.98780 | 0.28685 | 0.2904 | 0.28032 |
BMO-20 | 0.98792 | 0.28669 | 0.2902 | 0.28065 |
Table 1 Lattice parameters and cell volumes of MO, BMO-50, BMO-30 and BMO-20
Sample | a/nm | c/nm | c/a | V/nm3 |
---|---|---|---|---|
MO | 0.98723 | 0.28707 | 0.2908 | 0.27981 |
BMO-50 | 0.98742 | 0.28689 | 0.2905 | 0.28021 |
BMO-30 | 0.98780 | 0.28685 | 0.2904 | 0.28032 |
BMO-20 | 0.98792 | 0.28669 | 0.2902 | 0.28065 |
Fig.6 CV curves of α-MnO2 and Bi-doped α-MnO2 at scan rate of 5 mV/s(A), BMO-20(B) and MO(C) at different scan rates and specific capacitances of α-MnO2 and Bi-doped α-MnO2 at different scan rates(D)a. MO; b. BMO-50; c. BMO-30; d. BMO-20.
Fig.7 Galvanostatic charge/discharge curves of α-MnO2 and Bi-doped α-MnO2(A) and cycle performance of α-MnO2 and Bi-doped α-MnO2(current density: 1 A/g)(B)a. MO; b. BMO-50; c. BMO-30; d. BMO-20.
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