Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (9): 1611.doi: 10.7503/cjcu20160401
• Analytical Chemistry • Previous Articles Next Articles
ZHUANG Qianfen1, CAO Wei1, WU Qi1, NI Yongnian1,2,*(
)
Received:2016-06-06
Online:2016-09-10
Published:2016-08-23
Contact:
NI Yongnian
E-mail:ynni@ncu.edu.cn
Supported by:CLC Number:
TrendMD:
ZHUANG Qianfen, CAO Wei, WU Qi, NI Yongnian. Fluorescence Detection of Au(Ⅲ) Based on Carbon Nitride Nanoparticles†[J]. Chem. J. Chinese Universities, 2016, 37(9): 1611.
Scheme 1 Fluorescent detection of Au3+ ions based on fluorescent carbon nitride nanoparticles
Fig.1 TEM image(A) and FTIR spectrum(B) of carbon nitride nanoparticles
Fig.2 Fluorescence emission spectra of carbon nitride nanoparticles with varying excitation(A) and UV-Vis absorption(a), fluorescence excitation(b) and emission(c) spectra of carbon nitride nanoparticles(B) Inset of (B): photograph of carbon nitride nanoparticles under UV light irradiation at 365 nm.
Fig.3 Fluorescence response of carbon nitride nanoparticles in the presence of different concentrations of Au(Ⅲ)(A) and plot of F/F0 vs. Au(Ⅲ) concentrations(B) (A) Concentrations of Au(Ⅲ) from top to bottom/(μmol·L-1): 0, 0.001, 0.005, 0.010, 0.025, 0.050, 0.10, 0.25, 0.50, 0.75, 1.00, 2.00, 3.00, 4.00, 5.00, 6.00, 7.00, 8.00, 9.00, 10.0, 11.0, 12.0, 13.0, 14.0. Inset of (B): linear relationship between F/F0 and Au(Ⅲ) concentrations in the range of 0.050 to 11.0 μmol/L. The error bar represents average value plus or minus one standard deviation for three measurements.
| Fluorescent probe | Linear range/(μmol·L-1) | LOD/(μmol·L-1) | Ref. |
|---|---|---|---|
| N,S-GQDs | 0.10—50 | 0.05 | [ |
| Aryl alkyne compound | 0.10—0.50 | 0.32 | [ |
| 4-Propargylamino-1,8-naphthalimide | 0.00—60 | 8.44 | [ |
| Thioamide-phenyl-substituted alkynes | 0.50—15 | 0.39 | [ |
| GO-PVA | 0.70—300 | 0.70 | [ |
| CTPA-modified silica nanoparticles | 0.50—100 | 0.023 | [ |
| Carbon nitride nanoparticles | 0.05—11.0 | 0.0226 | This work |
Tabel 1 Comparison of detection of Au(Ⅲ) with various fluorescence probes
| Fluorescent probe | Linear range/(μmol·L-1) | LOD/(μmol·L-1) | Ref. |
|---|---|---|---|
| N,S-GQDs | 0.10—50 | 0.05 | [ |
| Aryl alkyne compound | 0.10—0.50 | 0.32 | [ |
| 4-Propargylamino-1,8-naphthalimide | 0.00—60 | 8.44 | [ |
| Thioamide-phenyl-substituted alkynes | 0.50—15 | 0.39 | [ |
| GO-PVA | 0.70—300 | 0.70 | [ |
| CTPA-modified silica nanoparticles | 0.50—100 | 0.023 | [ |
| Carbon nitride nanoparticles | 0.05—11.0 | 0.0226 | This work |
Fig.4 Selectivity of the sensor based on fluorescence of graphitic carbon nitride for Au(Ⅲ) detection a. Blank; b. Au3+; c. Fe3+; d. Al3+; e. Cr3+; f. Co2+; g. Ni2+; h. Pb2+; i. Cd2+; j. Mn2+; k. Ce2+; h. Cu2+; m. Mg2+; n. Ba2+; o. Fe2+; p. Ag+; q. Na+. Concentration of metal ions is 10.0 μmol/L. The error bar represents average value±standard deviation(n=3).
| Sample | Added/(μmol·L-1) | Founda/(μmol·L-1) | Average recoveryb(%) |
|---|---|---|---|
| 1 | 1.00 | 1.07±0.03 | 107 |
| 2 | 2.00 | 1.86±0.06 | 93 |
| 3 | 4.00 | 3.71±0.03 | 93 |
Table 2 Detection of Au(Ⅲ) spiked in lake samples(n=3)
| Sample | Added/(μmol·L-1) | Founda/(μmol·L-1) | Average recoveryb(%) |
|---|---|---|---|
| 1 | 1.00 | 1.07±0.03 | 107 |
| 2 | 2.00 | 1.86±0.06 | 93 |
| 3 | 4.00 | 3.71±0.03 | 93 |
| [1] | Jin P., Dai Z., Guo W. J., Chen G. P., Chem. J. Chinese Universities,2015, 36(5), 844—849 |
| (金萍, 代昭, 郭文娟, 陈广平. 高等学校化学学报, 2015, 36(5), 844—849) | |
| [2] | Huang L. J., Zhang L. H., Mao H. J., Wang P., Jiang Y. X., Li P. P., Jin Q. H., Zhao J. L., Chem. J. Chinese Universities,2015, 36(9), 1687—1693 |
| (黄丽君, 张丽华, 毛红菊, 王萍, 蒋友旭, 李盼盼, 金庆辉, 赵建龙. 高等学校化学学报, 2015, 36(9), 1687—1693) | |
| [3] | Chen W. W., Guo Y. M., Zheng W. Q., Xianyu Y. L., Wang Z., Jiang X. Y., Chin. J. Anal. Chem., 2014, 42(3), 307—316 |
| (陈雯雯, 郭永明, 郑问枢, 鲜于运雷, 王卓, 蒋兴宇, 分析化学, 2014, 42(3), 307—316) | |
| [4] | Arcadi A., Chem.Rev., 2008, 108(8), 3266—3325 |
| [5] | Zhou Y. Y., Tang L., Zeng G. M., Zhang C., Zhang Y., Xie X., Sensor Acta B,2016, 223, 280—294 |
| [6] | Wu Y., Lai R. Y., Anal. Chem., 2016, 88, 2227—2233 |
| [7] | Glisic B. D., Rychlewska U., Djuran M. I., Dalton Trans., 2012, 41, 6887—6901 |
| [8] | Ott I., Coord.Chem.Rev., 2009, 253, 1670—1681 |
| [9] | Kazemi E., Dadfarnia S., Shabani A. M. H., Talanta,2015, 141, 273—278 |
| [10] | Butler O. T., Cook J. M., Harrington C. F., Hill S. J., Rieuwerts J., Miles D. L., J. Anal. At. Spectrom., 2007, 22, 187—221 |
| [11] | Xu Z., Chen X., Kim H. N., Yoon J., Chem. Soc. Rev., 2010, 39, 127—137 |
| [12] | Seo H., Jun M. E., Ranganathan K., Lee K. H., Kim K. T., Lim W., Rhee Y. M., Ahn K. H., Org. Lett., 2014, 16, 1374—1377 |
| [13] | Chinapang P., Ruangpornvisuti V., Sukwattanasinitt M., Rashatasakhon P., Dyes Pigments,2015, 112, 236—238 |
| [14] | Tang Y., Su Y., Yang N., Zhang L., Lv Y., Anal. Chem., 2014, 86, 4528—4535 |
| [15] | Zhou J., Yang Y., Zhang C. Y., Chem. Commun., 2013, 49, 8605—8607 |
| [16] | Yang T. T., Cai F., Zhang X. D., Huang Y. M., RSC Adv., 2015, 5, 107340—107347 |
| [17] | Su J. Y., Zhu L., Geng P., Chen G. H., J. Hazard. Mater., 2016, 316, 159—168 |
| [18] | Do J. H., Kim H. N., Yoon J., Kim J. S., Kim H. J., Org. Lett., 2010, 12, 932—934 |
| [19] | Chio J. Y., Kim G. H., Guo Z., Lee H. Y., Swamy K. M. K., Shin J. Pai S., Shin I., Yoon J.,Biosens. Bioelectron., 2013, 49, 438—441 |
| [20] | Cao X., Lin W., Ding Y., Chem. Eur. J., 2011, 17, 9066—9069 |
| [21] | Kundu A., Layek R. K., Kuila A., Nandi A. K., ACS Appl. Mater. Interfaces,2012, 4, 5576—5582 |
| [22] | Song Z., Xiao C., Dai Y., Fei Q., Huan Y., Feng G., Nanotechnology,2012, 23, 425501—425507 |
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