Photocatalytic Reduction Performance of Z-scheme Two-dimensional BCN/Sn3O4 Composite Materials

doi:10.7503/cjcu20210470

Abstract

Abstract:

The research on the Z-Scheme heterostructure composition of carbon nitride-based polymer mate- rial is an important strategy to improve its photocatalytic performance. Two-dimensional boron-doped carbon nitride（BCN） and Tin tetroxide（Sn₃O₄） semiconductor materials were prepared by direct thermal polymerization and hydrothermal synthesis， respectively. And BCN/Sn₃O₄ composites were constructed by ultrasonic composite and calcined composite methods. The prepared samples were characterized and analyzed by means of X-ray diffraction（XRD）， ultraviolet-visible diffuse reflectance（UV-Vis）， transmission electron microscopy（TEM）. The microstructure and photoelectric properties of the catalyst prepared from different methods were discussed. At the same time， the photocatalytic performance of the catalysts was investigated by using visible light photolysis of water to produce hydrogen and activated oxygen to produce hydrogen peroxide. The results showed that BCN and Sn₃O₄ can form a two-dimensional surface-to-surface composite structure， and compared to the ultrasonic composite method， the direct calcination method is more conducive for the formation of an effective interface， causing the charge transfer from Sn₃O₄ to BCN between the interface and enhancing the surface charge density of BCN. This composite material had much optimized photoelectric response and photocatalytic reduction activity. Among them， the sample BCN/Sn₃O₄-3C（mass ratio of Sn₃O₄/BCN=3%） prepared by calcination method showed significantly enhanced photolysis of water to produce hydrogen and activated oxygen to produce hydrogen peroxide. This work provides a new research idea for the construction of carbon nitride-based Z-scheme photocatalytic systems.

Key words: Boron-doped carbon nitride, Two-dimensional composite, Z-type heterojunction, Hydrogen production, Activate oxygen

CLC Number:

O643

TrendMD:

WANG Yishu, LI Xue, YAN Li, XU Hongyun, ZHU Yuxin, SONG Yanhua, CUI Yanjuan. Photocatalytic Reduction Performance of Z-scheme Two-dimensional BCN/Sn₃O₄ Composite Materials[J]. Chem. J. Chinese Universities, 2021, 42(12): 3722.

Figures/Tables 9

References 33

1	Wang Z.， Li C.， Domen K.， Chem. Soc. Rev.， 2019， 48（7）， 2109—2125
2	Lei Y. F.， Lei S. B.， Piao. Y.， Prog. Chem.， 2021， 33（1）， 66—77
3	Han X.， Zhang Y. H.， Tian N.， Ma T. Y.， Huang H. W.， Wang S. B.， Small Structures， 2021， 2， 2000061
4	Chen T.， Liu L. Z.， Hu C.， Huang H. W.， Chinese J. Catal.， 2021， 42（9）， 1413—1438
5	Naseri A.， Samadi M.， Pourjavadi A.， Moshfegh A. Z.， Ramakrishna S.， J. Mater. Chem. A， 2017， 5（45）， 23406—23433
6	Fang Y. X.， Zheng Y.， Fang T.， Chen Y.， Zhu Y. D.， Liang Q.， Sheng H.， Li Z. S.， Chen C. C.， Wang X. C.， Sci. China Chem.， 2020， 63（2）， 149—181
7	Zhu Y. X.， Ouyang J.， Song Y. H.， Tang S.， Cui Y. J.， Chem. J. Chinese Universities， 2020， 41（7）， 1645—1652（祝玉鑫，欧阳杰，宋艳华，唐盛，崔言娟. 高等学校化学学报， 2020， 41（7）， 1645—1652）
8	Wang X. Y.， Meng J. Q.， Zhang X. Y.， Liu Y. Q.， Ren M.， Yang Y. X.， Guo Y. H.， Adv. Funct. Mater.， 2021， 31（20）， 2010763
9	Xu Z.， Yu X. G.， Shan Y.， Liu F. F.， Zhang X. M.， Chen K. Z.， J. Inorg. Mater.， 2017， 32（2）， 155—162（徐赞，于薛刚，单妍，刘峰峰，张宪明，陈克正. 无机材料学报， 2017， 32（2）， 155—162）
10	Yan Q.， Huang G. F.， Li D. F.， Zhang M.， Pan A. L.， Huang W. Q.， J. Mater. Sci. Technol.， 2018， 34（12）， 2515—2520
11	Xu Q. L.， Zhang L. Y.， Yu J. G.， Wageh S.， Al⁃Ghamdi A. A.， Jaroniec M.， Mater. Today， 2018， 21（10）， 1042—1063
12	Jiang L. B.， Yuan X. Z.， Zeng G. M.， Liang J.， Wu Z. B.， Wang H.， Environ. Sci⁃Nano， 2018， 5（3）， 599—615
13	Liu D.， Chen S. T.， Li R. J.， Peng T. Y.， Acta Phys. Chim Sin.， 2021， 37（6）， 2010017
14	He Y. H.， Controllable Synthesis and Properties of Sn3O4⁃based Photocatalytic Materials， Fuzhou University， Fuzhou， 2014（何运慧. Sn₃O₄基光催化材料的控制合成及性能研究，福州：福州大学， 2014）
15	Cui L.， Yang L. J.， Wang F.， Xia W. W.， J. Inorg. Mater.， 2016， 31（5）， 461—465（崔磊，杨丽娟，王帆，夏炜炜. 无机材料学报， 2016， 31（5）， 461—465）
16	Yang L. Q.， Lv M. F.， Song Y.， Yin K. Y.， Wang X. L.， Cheng X. L.， Cao K. S.， Li S. T.， Wang C.， Yao Y. F.， Luo W. J.， Zou Z. G.， Appl. Catal. B： Environ.， 2020， 279， 119341
17	Hu J. L.， Li X. Y.， Wang X. D.， Li Q. S.， Wang F.， Dalton T.， 2019， 48（24）， 8937—8947
18	Li C. M.， Yu S. Y.， Dong H. J.， Liu C. B.， Wu H. J.， Che H. N.， Chen G.， Appl. Catal. B： Environ.， 2018， 238， 284—293
19	Yang R. Q.， Ji Y. C.， Zhang J.， Zhang R. T.， Liu F.， Chen Y. K.， Liang L. L.， Han S. W.， Yu X.， Liu H.， Catal. Today， 2019， 335， 520—526
20	Wang X. X.， Gao J. P.， Zhao R. R.， Wu Y. L.， Hao C. Y.， Qiu H. X.， Chinese J. Inorg. Chem.， 2018， 34（6）， 1059—1064（王晓雪，高建平，赵瑞如，吴永利，郝超月，邱海霞. 无机化学学报， 2018， 34（6）， 1059—1064）
21	Xu W.， Li M.， Chen X. B.， Zhao J. H.， Tan R. Q.， Li R.， Li J.， Song W. J.， Mater. Lett.， 2014， 120， 140—142
22	Wang Y. X.， Wang H.， Chen F. Y.， Cao F.， Zhao X. H.， Meng S. G.， Cui Y. J.， Appl. Catal. B： Environ.， 2017， 206， 417—425
23	Zhang G. G.， Li G. S.， Lan Z. A.， Lin L. H.， Savateev A.， Heil T.， Zafeirators S.， Wang X. C.， Antonietti M.， Angew. Chem. Int. Ed.， 2017， 56（43）， 13445—13449
24	Zima T.， Bataev I.， J. Solid State Chem.， 2016， 243， 282—289
25	Sun L. H.， Xiao H. M.， Cong S. N.， Hao Y. J.， Xue M. R.， Kang S. Z.， Inorg. Chem. Commun.， 2019， 106， 116—119
26	Kumar A.， Kumar P.， Joshi C.， Ponnada S.， Pathak A. K.， Ali A.， Sreedhar B.， Jain S. L.， Green Chem.， 2016， 18（8）， 2514—2521
27	Khan M. A.， Mutahir S.， Wang F. Y.， Lei W.， Xia M. Z.， Zhu S. D.， J. Hazard. Materials， 2019， 367， 293—303
28	Balgude S. D.， Sethi Y. A.， Kale B. B.， Amalnerkar D. P.， Adhyapak P. V.， RSC Adv.， 2019， 9（18）， 10289—10296
29	Xu Q. L.， Zhu B. C.， Jiang C. J.， Cheng B.， Yu J. G.， Solar RRL， 2018， 2（3）， 1800006
30	Tian N.， Zhang Y. H.， Li X. W.， Xiao K.， Du X.， Dong F.， Waterhouse G. I. N.， Zhang T. R.， Huang H. W.， Nano Energy， 2017， 38， 72—81
31	Yu T.， Breslin C. B.， J. Electrochem. Soc.， 2020， 167（12）， 126502
32	Zhang J. Z.， Zheng L. H.， Wang F.， Chen C.， Wu H. D.， Leghari S. A. K.， Long M. C.， Appl. Catal. B： Environ.， 2020， 269， 118770
33	Zhao X. S.， You Y. Y.， Huang S. B.， Wu Y. X.， Ma Y. Y.， Zhang G.， Zhang Z. H.， Appl. Catal. B： Environ.， 2020， 278， 119251

[1]	SONG Yingying, HUANG Lin, LI Qingsen, CHEN Limiao. Preparation of CuO/BiVO₄ Photocatalyst and Research on Carbon Dioxide Reduction [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220126.
[2]	CHEN Wangsong, LUO Lan, LIU Yuguang, ZHOU Hua, KONG Xianggui, LI Zhenhua, DUAN Haohong. Recent Progress in Photoelectrochemical H₂ Production Coupled with Biomass-derived Alcohol/aldehyde Oxidation [J]. Chem. J. Chinese Universities, 2022, 43(2): 20210683.
[3]	JIANG Shan, SHEN Qianqian, LI Qi, JIA Husheng, XUE Jinbo. Pd-loaded Defective TiO₂ Nanotube Arrays for Enhanced Photocatalytic Hydrogen Production Performance [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220206.
[4]	LI Shurong, WANG Lin, CHEN Yuzhen, JIANG Hailong. Research Progress of Metal⁃organic Frameworks on Liquid Phase Catalytic Chemical Hydrogen Production [J]. Chem. J. Chinese Universities, 2022, 43(1): 20210575.
[5]	XUE Jinbo, GAO Guoxiang, SHEN Qianqian, LIU Tianwu, LIU Xuguang, JIA Husheng. Construction of a Novel S-scheme CdS-BiVO₄ Heterojunction Photoelectrodes and Research on Hydrogen Production [J]. Chem. J. Chinese Universities, 2021, 42(8): 2493.
[6]	WU Qiliang, MEI Jinghao, LI Zheng, FAN Haidong, ZHANG Yanwei. Photo-thermal Coupling Water Splitting over Fe-doped TiO₂ with Various Nanostructures [J]. Chem. J. Chinese Universities, 2021, 42(6): 1837.
[7]	XU Anqi, LI Bin, DU Fanglin. Synthesis of Ordered Mesoporous TiO₂and Their Application for Hydrogen Production from Photocatalytic Water-splitting [J]. Chem. J. Chinese Universities, 2021, 42(4): 978.
[8]	SUN Dawei,LI Yuejun,CAO Tieping,ZHAO Yanhui,YANG Diankai. Preparation of Dy ³⁺-doped YVO₄/TiO₂ Composite Nanofibers with Three-dimensional Net-like Structure and Enhanced Photocatalytic Activity for Hydrogen Evolution ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2348.
[9]	DAI Hongyan, YANG Huimin, LIU Xian, JIAN Xuan, GUO Minmin, CAO Lele, LIANG Zhenhai. Preparation and Electrochemical Evaluation of MoS₂/graphene as a Catalyst for Hydrogen Evolution in Microbial Electrolysis Cell^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 351.
[10]	TIAN Yi, LI Yuexiang, PENG Shaoqin. Effect of Y₂O₃ Supporter on the Catalytic Hydrogen Production from an Aqueous Formaldehyde Solution Catalyzed by Metal Cu Loaded on Y₂O₃^† [J]. Chem. J. Chinese Universities, 2017, 38(10): 1841.
[11]	LU Yonghong, WU Pingxiao, HUANG Junyi, TRAN Lytuong, ZHU Nengwu, DANG Zhi. Alkaline-assisted Hydrothermal Fabrication of CdZnS with Enhanced Visible-light Photocatalytic Performance^† [J]. Chem. J. Chinese Universities, 2015, 36(8): 1563.
[12]	QU Yang, ZHOU Wei, REN Zhiyu, PAN Kai, JIANG Le, FU Honggang. Controllable Preparation of CdTiO₃ Nanorods and Their Photocatalytic Properties for Hydrogen Production^† [J]. Chem. J. Chinese Universities, 2014, 35(5): 995.
[13]	ZHAO Weiliang, LI Cong, HAN Xu, LI Tingting, ZHANG Guiju, GAN Xin, LI Fumin, FU Wenfu. Syntheses, Properties and Photocatalytic Hydrogen Evolution Efficiency of Cyclometalated Pt(Ⅱ) Complexes Bearing S-methylphenyl Group^† [J]. Chem. J. Chinese Universities, 2014, 35(10): 2214.
[14]	HAO Wei-Chang*, ZHAI Ting-Ting, WANG Xu, WANG Tian-Min. Fabrication and Catalytic Activity of Nickel Core-shell Structure [J]. Chem. J. Chinese Universities, 2010, 31(6): 1213.
[15]	ZHANG Xin-Rong, WANG Lu-Cun, YAO Cheng-Zhang, CAO Yong, DAI Wei-Lin, FAN Kang-Nian, WU Dong, SUN Yu-Han . Highly Effective Hydrogen Production from Steam Reforming of CH₃OH over Cu/ZnO/Al₂O₃ Catalysts Promoted by Nanostructured Carbon Materials [J]. Chem. J. Chinese Universities, 2004, 25(11): 2125.

Photocatalytic Reduction Performance of Z-scheme Two-dimensional BCN/Sn₃O₄ Composite Materials

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 9

References 33

Related Articles 15

Recommended Articles

Metrics

Comments