Preparation and Performance of Solid-state Electrochromic Devices Based on Polyaniline

Chem. J. Chinese Universities

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Preparation and Performance of Solid-state Electrochromic Devices Based on Polyaniline

CHEN Li-Xian², LU Yan-Ting², WENG Shao-Huang², ZHOU Jian-Zhang^1*, LIN Zhong-Hua¹

1. State Key Laboratory of Physical Chemistry of Solid Surfaces,
2. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China

Received:2008-05-26 Revised:1900-01-01 Online:2009-03-10 Published:2009-03-10
Contact: ZHOU Jian-Zhang

Abstract

Abstract: In this paper, by polymeric electrolyte(PMMA-PC-EC-LiClO₄), we introduced CeO₂-TiO₂ composite as the complementary electrode of a new solid-state dual-type polyaniline electrochromic device(ECD). The electrochromic performance of the dual-type ECD was characterized using in situ UV-Vis spectroscopy. Compared to single-type ECD(ITOPANIPEITO), the dual-type ECD showed better electrochromic performance such as less response time, longer cyclic lifetime. Also, the composition of the electrolyte was found to influence the cyclic stability of PANI. The optimized dual-type ECD exhibited reversible electrochromic behavior from yellow at bleached state(-1.5 V) to blue at colored state(1.0 V PANI vs. CeO₂-TiO₂) with good cyclic stability. The transmittance of the ECD at 700 nm changed from 42.19% to 13.35% with a coloration efficiency of 152.1 cm²/C.

Key words: Polyaniline, CeO₂-TiO₂ composite, Electrochromic device

CLC Number:

O646

TrendMD:

CHEN Li-Xian², LU Yan-Ting², WENG Shao-Huang², ZHOU Jian-Zhang^1*, LIN Zhong-Hua¹
. Preparation and Performance of Solid-state Electrochromic Devices Based on Polyaniline
[J]. Chem. J. Chinese Universities, doi: .

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Preparation and Performance of Solid-state Electrochromic Devices Based on Polyaniline

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