Chem. J. Chinese Universities ›› 2015, Vol. 36 ›› Issue (9): 1674.doi: 10.7503/cjcu20150184
• Analytical Chemistry • Previous Articles Next Articles
ZHUANG Qianfen1, WANG Yong1, NI Yongnian1,2,*()
Received:
2015-03-09
Online:
2015-09-10
Published:
2015-08-17
Contact:
NI Yongnian
E-mail:ynni@ncu.edu.cn
Supported by:
CLC Number:
TrendMD:
ZHUANG Qianfen, WANG Yong, NI Yongnian. Electrochemical Sensor for the Detection of Riboflavin Based on Nanocomposite Film of Polydeoxyadenylic Acid/Reduced Graphene Oxide†[J]. Chem. J. Chinese Universities, 2015, 36(9): 1674.
Fig.3 CV curves(A) and EIS responses(B) of different electrodes in 5.0 mmol/L [Fe(CN)6]3-/[Fe(CN)6]4-(1∶1) solution containing 0.1 mol/L KCla. Bare Au electrode; b. A32/Au electrode; c. RGO/A32/Au electrode; d. rMoS2-graphene/A32/Au electrode.
Fig.4 CV(A) and DPV(B) curves of different electrodes in the N2-saturated electrochemistry buffer solution containing 2.0 μmol/L riboflavina. Bare Au electrode; b. A32/Au electrode; c. RGO/A32/Au electrode.
Fig.5 CVs curves of RGO/A32/Au electrode with different scan rates in the N2-saturated electrochemistry buffer solution containing 2.0 μmol/L riboflavin(A), and the linear relationship between the anodic peak current and the square root of scan rate(B)Scan rates from inner to outer curves/(V·s-1): 0.01, 0.02, 0.03, 0.04, 0.05, 0.06, 0.07, 0.08, 0.09, 0.1, 0.11, 0.12, 0.13, 0.14, 0.15, 0.16, 0.17, 0.18, 0.19, 0.2.
Fig.6 DPV curves of the RGO/ A32/Au electrode with different concentrations of riboflavin in the N2-saturated electrochemistry buffer solutionConcentrations of riboflavin from a to y/(μmol·L-1): 0, 0.025, 0.05, 0.1, 0.25, 0.5, 0.75, 1.0, 1.25, 1.5, 1.75, 2.0, 2.25, 2.5, 2.75, 3.0, 3.5, 4.0, 4.5, 5.0, 6.0, 7.0, 8.0, 9.0, 10.0.
Fig.7 Plot of cathodic peak current for the RGO/ A32/Au electrode against riboflavin concentration in the N2-saturated electrochemistry buffer solutionInset: calibration curve of the electrode for riboflavin. The error bar on each datum point represents mean value plus or minus one standard deviation.
Method | Linear range/(μmol·L-1) | LOD/(μmol·L-1) | Reference |
---|---|---|---|
Electrochemistry | 0.1—200 | 0.05 | [ |
Electrochemistry | 1.33—186.0 | 0.903 | [ |
Electrochemistry | 0.323—40 | 0.187 | [ |
Electrochemistry | 0.2—100 | 0.107 | [ |
Electrochemistry | 0.009—55.9 | 0.001 | [ |
Electrochemistry | 0.3—0.8 | 0.10 | [ |
Electrochemistry | 0.025—2.25 | 0.02 | [ |
Fluorescence | 0.58—20 | 0.18 | [ |
Fluorescence | 0—265.7 | 1.59 | [ |
Electrochemistry | 0.025—2.75 | 0.015 | This work |
Table 1 Comparison of determination of riboflavin using various sensors
Method | Linear range/(μmol·L-1) | LOD/(μmol·L-1) | Reference |
---|---|---|---|
Electrochemistry | 0.1—200 | 0.05 | [ |
Electrochemistry | 1.33—186.0 | 0.903 | [ |
Electrochemistry | 0.323—40 | 0.187 | [ |
Electrochemistry | 0.2—100 | 0.107 | [ |
Electrochemistry | 0.009—55.9 | 0.001 | [ |
Electrochemistry | 0.3—0.8 | 0.10 | [ |
Electrochemistry | 0.025—2.25 | 0.02 | [ |
Fluorescence | 0.58—20 | 0.18 | [ |
Fluorescence | 0—265.7 | 1.59 | [ |
Electrochemistry | 0.025—2.75 | 0.015 | This work |
Fig.8 Plot of cathodic peak current for the RGO/ A32/Au electrode against riboflavin(2.0 μmol/L) with and without other bioactive substance(100.0 μmol/L)a. Riboflavin; b. riboflavin+ascorbic acid; c. riboflavin+vitamin B6; d. riboflavin+nicotinamide; e. riboflavin+thiamine; f. riboflavin+glucose; g. riboflavin+lysine; h. riboflavin+folic acid; i. riboflavin+uric acid.
Sample | Added/(μmol·L-1) | Founda/(μmol·L-1) | Mean recoveryb(%) |
---|---|---|---|
1 | 0.25 | 0.26±0.02 | 104 |
2 | 1.0 | 1.07±0.08 | 107 |
3 | 2.0 | 1.96±0.04 | 98 |
Table 2 Determination of riboflavin spiked in urine samples(n=3)
Sample | Added/(μmol·L-1) | Founda/(μmol·L-1) | Mean recoveryb(%) |
---|---|---|---|
1 | 0.25 | 0.26±0.02 | 104 |
2 | 1.0 | 1.07±0.08 | 107 |
3 | 2.0 | 1.96±0.04 | 98 |
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