Synergistic Catalysis of Fe2O3 and TiF3 Additives on the LiBH4-MgH2 Composite

doi:10.3969/j.issn.0251-0790.2012.04.024

Chem. J. Chinese Universities ›› 2012, Vol. 33 ›› Issue (04): 781.doi: 10.3969/j.issn.0251-0790.2012.04.024

• Physical Chemistry • Previous Articles Next Articles

Synergistic Catalysis of Fe₂O₃ and TiF₃ Additives on the LiBH₄-MgH₂ Composite

ZHANG Hui^1,2, ZHOU Yi-Xi^1,2, SUN Li-Xian², CAO Zhong¹, XU Fen³, LIU Shu-Sheng², ZHANG Jian², SONG Li-Fang², SI Xiao-Liang², JIAO Cheng-Li², WANG Shuang², LI Zhi-Bao², LIU Shuang², LI Fen²

1. School of Chemistry & Biological Engineering, Changsha University of Science and Technology, Changsha 410004, China;
2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;
3. Chemistry and Chemical Engineering School, Liaoning Normal University, Dalian 116029, China

Received:2011-09-14 Online:2012-04-10 Published:2012-04-10
Supported by:
国家"九七三"计划项目(批准号: 2010CB631303)、国家自然科学基金(批准号: 20833009, 51071146, 21173111, 20903095, 51071081, 51101145, U0734005, 51102230)和广东省-中国科学院联合基金(批准号: 2010A090100034)资助.

Abstract

Abstract: Five systems(2LiBH₄-MgH₂, 2LiBH₄-MgH₂-10%Fe₂O₃, 2LiBH₄-MgH₂-10%TiF₃, 2LiBH₄-MgH₂-5%Fe₂O₃-5%TiF₃ and 2LiBH₄-MgH₂-10%Fe₂O₃-10%TiF₃) were prepared by ball milling. They were investigated through thermogravimeteric analysis(TG), diffraction scanning calorimetric(DSC), powder X-ray diffraction(XRD), Fourier transformed infrared spectrometer(FTIR) and pressure-content-temperature(PCT). The addition of Fe₂O₃ and TiF₃ improved the hydrogen release property of the LiBH₄-MgH₂ complex system effectively. Especially, the codoped system(2LiBH₄-MgH₂-10%Fe₂O₃-10%TiF₃) starts to release hydrogen at around 110 ℃ and can release as much as 9.6%. Besides, the results of PCT show that the codoped system(2LiBH₄-MgH₂-5%Fe₂O₃-5%TiF₃) can release about 8.6% hydrogen within 10 min at 400 ℃. The properties of the codoped system are better than the other two single doped systems, which partly incarnated the synergistic catalysis of Fe₂O₃ and TiF₃.

Key words: LiBH₄, MgH₂, Fe₂O₃, TiF₃, Synergistic catalysis

CLC Number:

TrendMD:

ZHANG Hui, ZHOU Yi-Xi, SUN Li-Xian, CAO Zhong, XU Fen, LIU Shu-Sheng, ZHANG Jian, SONG Li-Fang, SI Xiao-Liang, JIAO Cheng-Li, WANG Shuang, LI Zhi-Bao, LIU Shuang, LI Fen. Synergistic Catalysis of Fe₂O₃ and TiF₃ Additives on the LiBH₄-MgH₂ Composite[J]. Chem. J. Chinese Universities, 2012, 33(04): 781.

References

Related Articles 15

[1]	YANG Jingyi, LI Qinghe, QIAO Botao. Synergistic Catalysis Between Ir Single Atoms and Nanoparticles for N₂O Decomposition [J]. Chem. J. Chinese Universities, 2022, 43(9): 20220388.
[2]	YAO Yiting, LYU Jiamin, YU Shen, LIU Zhan, LI Yu, LI Xiaoyun, SU Baolian, CHEN Lihua. Preparation of Hierarchical Microporous-mesoporous Fe₂O₃/ZSM-5 Hollow Molecular Sieve Catalytic Materials and Their Catalytic Properties for Benzylation [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220090.
[3]	ZHANG Weiguo, FAN Songhua, WANG Hongzhi, YAO Suwei. Synthesis of Self-assembled α-Fe₂O₃/Graphene Hydrogel for Supercapacitors with Promising Electrochemical Properties [J]. Chem. J. Chinese Universities, 2020, 41(8): 1850.
[4]	AI Cuiling,WU Lina,ZHANG Rongrong,SHAO Xiangwen,XU Junge. Synthesis and Antibacterial Performance of γ-Fe₂O₃/Ag/Ti $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 645.
[5]	CONG Rimin, YU Huaiqing, LUO Yunjun, LI Jiao, WANG Weiwei, LI Qiuhong, SUN Wuzhu, SI Weimeng, ZHANG Hua. Synthesis and Properties of Bi₂₅FeO₄₀/α-Fe₂O₃ Composite Nanoparticle Photocatalysts^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 629.
[6]	HAN Zhiying, LI Youji, LIN Xiao, WANG Ziyu, LI Ziqin, WANG Hao. Preparation and Photoelectrocatalytic Performance of Fe₂O₃/ZnO Composite Electrode Loading on Conductive Glass^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 771.
[7]	WANG Jinshuang, QIN Chuanli, WANG Hongjian, LI Jiadong, ZHANG Xuliang, CHEN Shuangying, JING Liqiang. Modification of Nano-sized Fe₂O₃ Photocatalysts with N-doped Graphene and g-C₃N₄ ^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 246.
[8]	GU Run, ZHANG Ming, WANG Chunyang, HUANG Weijun, LIU Dongming. Dehydrogenation Property and Mechanism of 3LiBH4/CeF3System [J]. Chem. J. Chinese Universities, 2016, 37(4): 688.
[9]	GONG Xue-Jing, CHENG Li-Ping, XU Bao-En, ZENG Yan-Li, LI Xiao-Yan, MENG Ling-Peng. Effects of Mg Substitution on Structure and Hydrogen Storage of LiBH₄(010) Surface [J]. Chem. J. Chinese Universities, 2013, 34(8): 1929.
[10]	LIU Hao, XU Fen, SUN Li-Xian, CAO Zhong, ZHOU Huai-Ying. Preparation and Hydrogen Generation for Al-LiBH₄ Composite Materials [J]. Chem. J. Chinese Universities, 2013, 34(8): 1953.
[11]	WU Ping, DU Ning, ZHANG Hui, YANG De-Ren, LU Tian-Hong. Synthesis and Lithium Storage Performance of α-Fe₂O₃-Ag Hybrid Nanorod Anode for Lithium-ion Batteries [J]. Chem. J. Chinese Universities, 2013, 34(3): 668.
[12]	KOU Hua-Qin, SANG Ge, CHEN Li-Xin, XIAO Xue-Zhang, DENG Shuai-Shuai, HUANG Zhi-Yong. Grain Size Effect of MgH₂ on Dehydrogenation Kinetics of 2LiBH₄+MgH₂ System [J]. Chem. J. Chinese Universities, 2013, 34(10): 2347.
[13]	ZHANG Zhi-Ming, LI Qiong, WANG Yue, CUI Zhi-Jie, YU Liang-Min. Synthesis and Characterization of Electromagnetic Functionalized Polyoyrrole/γ-Fe₂O₃ Nanospheres by Chemical One-step Method [J]. Chem. J. Chinese Universities, 2012, 33(09): 2106.
[14]	MA Xiao-Dong, GUO Hong-Wen, LÜ Lu, HE Xuan, FENG Xi. Preparation, Characterization and Gas Sensing Performance of Ag-supported α-Fe₂O₃ Hybrid [J]. Chem. J. Chinese Universities, 2012, 33(09): 1915.
[15]	LIU Gui-Feng, GAO Zhong-Li, YU Qiong, ZHANG Hui-Mao, WANG Zhen-Xin. Light Induced Cellular Cytotoxicity of Rich Arginine Peptide Modified Ferric Oxide Core Gold Shell Nanoparticles [J]. Chem. J. Chinese Universities, 2012, 33(09): 1920.

Synergistic Catalysis of Fe₂O₃ and TiF₃ Additives on the LiBH₄-MgH₂ Composite

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments