HRhCO(TPPTS)3/HAP Hydroformylate 1-Hexene High Selectivity and Special Isomerization Performance

doi:10.3969/j.issn.0251-0790.2012.08.036

Abstract

Abstract: Water-soluble rhodium-phoshpine complex HRhCO(TPPTS)₃ and TPPTS were supported by hydroxyapatite(HAP). The catalysts were characterized by FTIR, solid state ³¹P CP-MAS NMR, SEM, ICP-OES, and N₂ adsorption-desorption measurements. The catalysts showed special isomerization performance for 1-hexene, 2-hexene and 3-hexene. The results show high activity and selectivity in the hydroformylation of 1-hexene. Selectivity of 100% of aldehydes and high turnover frequency(TOF=2465 h^-1) were obtained under optimum condition. The catalysts could be easily separated from organic products and reused. The mechanism of isomerization performance of the catalyst and supporting HRhCO(TPPTS)₃ on HAP were discussed.

Key words: Hydroxyapatite, Heterogeneous hydroformylation, 1-Hexene, HRhCO(TPPTS)₃, Isomerization

CLC Number:

O643.3

TrendMD:

ZHANG Ding-Lin, FU Hai-Yan, ZHAO Xian-Ying, ZHAO Hua-Wen, CHEN Hua, LIU Yi-Min, LI Xian-Jun. HRhCO(TPPTS)₃/HAP Hydroformylate 1-Hexene High Selectivity and Special Isomerization Performance[J]. Chem. J. Chinese Universities, 2012, 33(08): 1835.

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HRhCO(TPPTS)₃/HAP Hydroformylate 1-Hexene High Selectivity and Special Isomerization Performance

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