High Performance Lithium-sulfur Battery with Hydroxyapatite Nanowire Composite Interlayer

doi:10.7503/cjcu20200012

Abstract

Abstract: Hydroxyapatite[Ca₅(PO₄)₃(OH)] nanowires were prepared by hydrothermal synthesis, and were combined as a polysulfide absorbent with multi-walled carbon nanotubes(MWCNTs) interlayer to form a hierarchically cross-linked hydroxyphosphate nanowire composite(HN/CNT) interlayer. This layer was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy(FTIR)and ultraviolet-visible spectroscopy(UV-Vis). The results of electrochemical tests show that the Li-S battery with HN/CNT interlayer has a specific discharge capacity of 871 mA·h/g after 200 cycles at 1C, and the fading rate is only 0.031% per cycle.

Key words: Li-S battery, Shuttle effect, Hydroxyapatite, Carbon nanotube, Interlayer

CLC Number:

O646

TrendMD:

LI Rui, SUN Xiaogang, ZOU Jingyi, HE Qiang. High Performance Lithium-sulfur Battery with Hydroxyapatite Nanowire Composite Interlayer[J]. Chem. J. Chinese Universities, 2020, 41(8): 1866.

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