Synthesis, Optical and Thermal Properties of Novel Schiff Base Complexes Containing Porphyrin Copper(Ⅱ) and Zinc(Ⅱ)

Abstract

Abstract: 5-(p-Benzylideneamino)phenyl-10, 15, 20-triphenylporphyrin copper(Ⅱ), zinc(Ⅱ) complexes and 5-[p-(4-nitrobenzylideneamino)]phenyl-10, 15, 20-triphenylporphyrin copper(Ⅱ), zinc(Ⅱ) complexes were designed and synthesized by the reaction of pyrrole and benzaldehyde et al.. The intermediates and target compounds were characterized by FTIR, FAB-MS, UV-Vis spectra and ¹H NMR. Furthermore, one of the target compounds was confirmed by single crystal X-ray diffraction.In addition, we also studied the thermostability and luminescent effect of the target compounds.The experiment results show that the strongest luminescent wavelength is 600 nm, which locates in the visible light area. The compounds decompose at 70 ℃ in the air.

Key words: Porphyrin, Schiff Base, Crystal

CLC Number:

O614
O627.12

TrendMD:

LUO Guo-Tian*, ZHENG Sheng-Wei, XU Qing-Bing. Synthesis, Optical and Thermal Properties of Novel Schiff Base Complexes Containing Porphyrin Copper(Ⅱ) and Zinc(Ⅱ)[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Optical and Thermal Properties of Novel Schiff Base Complexes Containing Porphyrin Copper(Ⅱ) and Zinc(Ⅱ)

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