Grafting Acrylic Acid onto Pre-irradiated Polypropylene by Reactive Extrusion

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Grafting Acrylic Acid onto Pre-irradiated Polypropylene by Reactive Extrusion

CAI Chuan-Lun^1,2, XIN Zhi-Rong³, YAO Zhan-Hai¹, SHI Qiang^1,2, YIN Jing-Hua¹

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China;
3. College of Biology & Chemistry, Yantai University, Yantai 264005, China

Received:2006-03-09 Revised:1900-01-01 Online:2006-10-10 Published:2006-10-10
Contact: YIN Jing-Hua

Abstract

Abstract:

Polypropylene functionalized with acrylic acid(PP-g-AA) was prepared by coupling electron beam(EB) pre-irradiation treatment with reactive extrusion process. The grafting samples were characterized by chemical titration, FTIR, polarized light microphotographs, DSC and WAXD. The study showed that grafting degree(Gd) increased with increasing irradiation dose and then leveled off; the Gd increased linearly with the AA concentration rising. It was observed that crystallization temperature of the grafted sample increased and crystallite size decreased, which can be attributed to the heterogeneous nucleating action of grafting chain. The MFR and mechanical properties measurements proved that serious degradation of PP occured in the stage of pre-irradiation and extruding process. Meanwhile, a mechanism of grafting reactions was proposed tentatively.

Key words: Polypropylene, Reactive extrusion, Electron beam pre-irradiation, Acrylic acid

CLC Number:

O631

TrendMD:

CAI Chuan-Lun^1,2, XIN Zhi-Rong³, YAO Zhan-Hai¹, SHI Qiang^1,2, YIN Jing-Hua¹. Grafting Acrylic Acid onto Pre-irradiated Polypropylene by Reactive Extrusion[J]. Chem. J. Chinese Universities, doi: .

[1]	JIANG Shenghan, CAO Changlin, XIAO Liren, YANG Tang, QIAN Qingrong, CHEN Qinghua. Preparation of Composite Semiconductor Micro-sheets with UV Shielding Performance and Its Application in Polypropylene [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220071.
[2]	ZHOU Chengsi, ZHAO Yuanjin, HAN Meichen, YANG Xia, LIU Chenguang, HE Aihua. Regulation of Silanes as External Electron Donors on Propylene/butene Sequential Polymerization [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220290.
[3]	DU Bin, CHEN Shangtao, ZHANG Fengbo, SHI Xingbo, LI Rongbo. Nonlinear Rheological Behavior of Long Chain Branching Polypropylene [J]. Chem. J. Chinese Universities, 2021, 42(6): 2034.
[4]	HUANG Huilong, HUANG Hanxiong. Low-temperature Impact Behavior of Droplet on Injection-compression Molded Nanostructured PP/POE Blend Surfaces [J]. Chem. J. Chinese Universities, 2021, 42(10): 3195.
[5]	AN Yue, HUANG Hanxiong. Condensate Microdrop Dynamic Behavior on Injection-compression Molded Bionic Polypropylene Nanosurfaces [J]. Chem. J. Chinese Universities, 2020, 41(8): 1888.
[6]	ZHANG Jihua,WANG Chao,ZAO Weitao,LI Li,LIU Xiaoyan,YANG Yuan,WANG Hao. Preparation of High-performance Montmorillonite/hydrogenated Butadiene-acrylonitrile Rubber by Using Electrostatic Interfaces [J]. Chem. J. Chinese Universities, 2020, 41(4): 803.
[7]	LIU Xuan, LIU Haoyu, LI Yifeng, ZHAO Jiaohong, YANG Rui. Infectious Effect of Organic Small Molecules on Photo-oxidative Aging of Polypropylene [J]. Chem. J. Chinese Universities, 2020, 41(12): 2838.
[8]	MA Yaping, ZHANG Ning, ZHENG Weiping, XIAO Weijia, LIU Chenguang, HE Aihua, SHAO Huafeng. Structures and Properties of Isotactic Polypropylene/Polybutene-1 In-reactor Alloys [J]. Chem. J. Chinese Universities, 2020, 41(12): 2851.
[9]	RAN Shiya,SHEN Haifeng,LI Xiaonan,WANG Zilu,GUO Zhenghong,FANG Zhengping. Effect and Mechanism of Rare Earth Trifluoromethanesulfonate on the Thermal Stability of Polypropylene^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1333.
[10]	SHAO Lu,LIANG Chunchao,XU Sheng,MI Puke,WANG Tinglan,YI Jianjun. Synthesis of Methylene-bridged Binuclear Metallocene Complexes and Application for Propylene Syndiospecific Polymerization^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1324.
[11]	SUN Guangdong, PAN Xiaopeng, ZHONG Yuhao, CHEN Enyu, HUANG Yi, SHAO Jianzhong. Photopolymerization Kinetics of Poly(Acrylate Acid) Hydrogels Induced by Blue Light ^† [J]. Chem. J. Chinese Universities, 2019, 40(11): 2404.
[12]	LUO Dajun, SHAO Huiju, JIN Jinbo, XIE Gaoyi, CUI Zhenyu, YU Jie, QIN Shuhao. Preparation of Hydrophilic Polypropylene/Polyvinyl Butyral Hollow Fiber Membranes by Melt-spinning-stretching^† [J]. Chem. J. Chinese Universities, 2018, 39(8): 1838.
[13]	HUANG Chenghuan, GUO Zhaoxia, YU Jian. Diffusion and Polymerization Behavior of Styrene in Polypropylene Pellets of Different Aggregation State^† [J]. Chem. J. Chinese Universities, 2018, 39(2): 382.
[14]	CHU Ming,ZHANG Jianfu,QU Lihang,LI Meiyuan,ZHU Dantong,LI Wenfei,YAO Zhanhai. Preparation and Properties of Grafted Polyethylene/GMS Grafted Modified SiO₂ Blends^† [J]. Chem. J. Chinese Universities, 2018, 39(12): 2781.
[15]	LI Hui, XING Zhe, LI Rong, ZHANG Mingxing, WANG Minglei, TAN Yizhe, WU Guozhong. Preparation of Cu²⁺-Chitosan Quaternary Ammonium Salt-g-Poly(acrylicacid) with Efficient Antibacterial Activity [J]. Chem. J. Chinese Universities, 2017, 38(5): 902.

Grafting Acrylic Acid onto Pre-irradiated Polypropylene by Reactive Extrusion

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments