Preparation and Properties of Grafted Polyethylene/GMS Grafted Modified SiO2 Blends†

doi:10.7503/cjcu20180345

Abstract

Abstract:

Dripping agricultural films can be obtained by adding dripping agents into the polymeric matrix, but the delaying and controlling migration of dripping agents is still challenging. Therefore, the graft of monostearic acid acrylic acid diglyceride(AGMS) and modified nano SiO₂(SiO₂-g-PAGMS) was prepared, and then the blend of AGMS, SiO₂-g-PAGMS, polyethylene, grafted polyethylene, modified SiO₂ were extruded in proportion and blown film. Acceleration dripping test at 60 ℃ showed that the maximum dripping duration of the film with SiO₂-g-PAGMS, polyethylene and grafted polyethylene compound could reach 36 d. Under the same conditions, it was 1.50 times and 2.25 times higher than the film of AGMS, polyethylene, grafted polyethylene compound, and SiO₂-g-PAGMS/polyethylene, respectively. Other results showed that haze and crystallization temperature of the grafted polyethylene compound/SiO₂-g-PAGMS blend decreased, while melting temperature increased, and the change of tensile strength of film was less than 11%.

Key words: Nano SiO₂, Grafted polyethylene, Monostearic acid acrylic acid diglyceride, Drip

CLC Number:

O631

TrendMD:

CHU Ming,ZHANG Jianfu,QU Lihang,LI Meiyuan,ZHU Dantong,LI Wenfei,YAO Zhanhai. Preparation and Properties of Grafted Polyethylene/GMS Grafted Modified SiO₂ Blends^†[J]. Chem. J. Chinese Universities, 2018, 39(12): 2781.

Figures/Tables 12

Table 1 Compositions of the LLDPE systems

Sample	m(FG)/g	m(LLDPE)/g	m(g1)/g	m(g2)/g	m(g3)/g	m(AGMS)/g	m(Modified nano SiO₂)/g
S1	96.4	100	3.6	0	0	0	0
S2	96.7	100	0	3.3	0	0	0
S3	96.8	100	0	0	3.2	0	0
S4	96.4	100	0	0	0	3.0	0.6
S5	97.0	100	0	0	0	3.0	0

Scheme 1 Synthesis procedure of modified SiO2(A), AGMS(B), SiO2-g-PAGMS(C) and LLDPE-g-AGMS(D)

Fig.1 FTIR spectra of modified SiO2(a), AGMS(b) and purified g1(c)

Fig.2 TGA curves of SiO2(a), modified SiO2(b), g1(c), g2(d) and g3(e)

Fig.3 Surface SEM images of LLDPE(A), S1(B), S2(C), S3(D), S4(E) and S5(F) films after placing for 30 d

Fig.4 Contact angles and typical images of LLDPE, S1—S5 films

Fig.5 FTIR spectra of purified LLDPE-g-AF(a), purified LLDPE-g-AGMS(b) and preirra-diated LLDPE(c)

Fig.6 Dripping properties of S1—S5 films

Fig.7 Picture of S2 film after 7 d accelerated dripping experimentInset: the typical contact angle image of S2 film before accelerated dripping exeriment.

Fig.8 DSC cooling(A) and melting(B) traces of S1—S5 blends

Table 2 Light transmission propeties of S1, S2, S3, S4 and S5 films

Sample	I_t(%)	I_s(%)
S1	85.76	25.05
S2	86.96	28.63
S3	86.35	29.01
S4	86.44	23.37
S5	87.72	29.62

Fig.9 Tensile strengths(A), elongation breaks(B) and tensile curves(C) of S1—S5 films

References 30

[1]	Sha P.Y., Liu Y., Xie L., Cui Z.C., Chem. J. Chinese Universities,2007, 28(11), 2205—2209
	(沙鹏宇, 刘岩, 谢雷, 崔占臣. 高等学校化学学报, 2007, 28(11), 2205—2209)
[2]	Gaikwad K.K., Lee S.M., Lee J.S., Lee Y.S., J. Food Meas. Charact.,2017, 11, 1706—1716
[3]	Babaghayou M.I., Mourad A. H.I., Lorenzo V., Chabira S.F., Sebaa M., Polym. Test,2018, 66, 146—154
[4]	Li Y.X., Fang X., Wang Y., Ma B.H., Sun J.Q., Chem. Mater.,2016, 28, 6975—6984
[5]	Li X.Z., Wang L., Pei Y.X., Jiang J.Q., Thin Solid Films,2014, 571, 127—133
[6]	Maechler L., Sarra-Bournet C., Chevallier P., Gherardi N., Laroche G., Plasma Chem. Plasma Process,2011, 31, 175—187
[7]	Zhang L., Qiao Z.A., Zheng M., Huo Q.S., Sun J.Q., J. Mater. Chem.,2010, 20, 6125—6130
[8]	Shlosman K., Suckeveriene R.Y., Rosen-Kligvasser J., Tchoudakov R., Zelikman E., Semiat R., Narkis M., Polym. Advan. Technol.,2014, 25, 1484—1491
[9]	Wei L.J., Yang F. X., Du Y. P.,J. Funct. Mater., 2017, (2), 2215—2220
	(魏丽娟, 杨福馨, 杜运鹏. 功能材料, 2017, (2), 2215—2220)
[10]	Zhang H.Y., Wu X.W., Cao D.W., Zhang Y.J., He M., Constr. Build. Mater.,2013, 47, 192—198
[11]	Laguna-Gutierrez E., Saiz-Arroyo C., Velasco J.I., Rodriguez-Perez M.A., Eur. Polym. J.,2016, 81, 173—185
[12]	Lin J., Zhong B.C., Jia Z.X., Hu D.C., Ding Y., Luo Y.F., Jia D.M., Appl. Surf. Sci.,2017, 407, 130—136
[13]	Chen D.Z., Chen F.X., Zhang H.W., Yin X.Z., Liu X., Zhou Y.S., Polym. Int.,2015, 64(12), 1741—1746
[14]	Wu X.H., Kang Q. H., Qian F. M., Jiang L. L., Fang K. M.,Acta Polymerica Sinica, 2015, (5), 596—601
	(吴小华, 康秋红, 钱方明, 蒋莉莉, 方克鸣. 高分子学报, 2015, (5), 596—601)
[15]	Rosen-Kligvasser J., Suckeveriene R.Y., Tchoudakov R., Narkis M., Polym. Eng. Sci., 2014, 54, 2023—2028
[16]	Rosen-Kligvasser J., Suckeveriene R.Y., Tchoudakov R., Narkis M., Polym. Advan. Technol.,2017, 28, 931—939
[17]	Ma Y.F., Wang J.Q., Guizhou Chemical Industry,2003, 6, 13—15
	(马玉富, 王继强. 贵州化工, 2003, 6, 13—15)
[18]	Wang J.H., Luo Q.Z., Wang Y.H., Li M.N., Zhang J., Wang D.S., Fine Chemicals,2007, 8, 751—754
	(王景慧, 罗青枝, 王彦红, 李敏娜, 张杰, 王德松. 精细化工, 2007, 8, 751—754)
[19]	Zhou Y.S., Yu J.R., Wang X.X., Wang Y., Zhu J., Hu Z.M., Fiber Polym.,2015, 16(8), 1772—1780
[20]	Li H. Y, Xue Y. H., Jia B., Bai Y., Zuo Y.Y., Wang S.G., Zhao Y.Y., Yang W.Z., Tang H.B., Carbohydr Polym.,2018, 188, 92—100
[21]	Kumar D., Kumar P., Pandey J., Int. J. Biol. Macromol.,2018, 115, 341—348
[22]	Villa F., Marengo M., Coninck J.D., Sci. Rep.,2018, 8, 6549
[23]	Lee K., Cho K., Park I., Lee B.H., Rana D., Choe S., J. Polym. Sci. Pol. Phys.,1999, 37, 1387—1395
[24]	Li W.F., Yao R.X., Yao Z.H., Liu S.M., Li L.X., J. Macromol. Sci., Part A: Pure Appl. Chem.,2016, 54(1), 47—51
[25]	Zeng Z.H., Feng G. M., Wei J. B.,China Plast, 1999, (13), 66—73
	(曾兆华, 冯冠民, 韦杰标. 中国塑料, 1999, (13), 66—73)
[26]	Shlosman K., Rosen-Kligvasser J., Suckeveriene R., Tchoudakov R., Narkis M., Eur. Polym. J.,2017, 90, 220—230
[27]	Tomacheski D., Pittol M., Ermel C.E., Simoes D.N., Ribeiro V.F., Santana R. M.C., Polym. Bull,2017, 74, 4841—4855
[28]	Abreu F. O. M. S., Forte M. M.C., Liberman S.A., J. Appl. Polym. Sci.,2005, 95, 254—263
[29]	Valenzuela C., Abugoch L., Tapia C., Lwt-Food Sci. Technol.,2013, 50, 531—537
[30]	Akyuz L., Kaya M., Ilk S., Cakmak Y.S., Salaberria A.M., Labidi J., Yilmaz B.A., Sargin I., Int. J. Biol. Macromol.,2018, 111, 475—484

Preparation and Properties of Grafted Polyethylene/GMS Grafted Modified SiO₂ Blends^†

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 12

References 30

Related Articles 1

Recommended Articles

Metrics

Comments