Electrochromic Composite Film and Device Based on Vanadium Tungstate and Congo Red

doi:10.7503/cjcu20200299

Abstract

Abstract:

The [PEI/P₂W₁₅V₃/PEI/CR]₂₀ film containing [P₂W₁₅V₃O₆₂]^8? anions, Congo red anions and poly- ethyleneimine cations was fabricated by layer-by-layer self-assembly technology through electrostatic attraction, and the [PEI/P₂W₁₅V₃]₂₀ film was also prepared by a similar method. The morphology and electrochromic properties of the films were studied by means of SEM, UV-Vis and electrochemical workstation. The results show that the composite film can realize the cyclic color change from light red to bluish violet and then to light red, and the electrochromic properties of [P₂W₁₅V₃O₆₂]^8? anions were well maintained. The light contrast of the film is 22.55%, the coloring efficiency can reach 122.67 cm²/C, the transmittance(in 500 nm) loss of the composite film is only 6.94% after 400 cycles, and its stability is good. The electrochromic device also realizes the color modulation from light red to bluish violet. This research will provide a reference for solving the problem of single color change of polyoxometalate electrochromic materials.

Key words: Polyoxometalate, Electrochromic property, Vanadium tungstate, Congo red

CLC Number:

O614

TrendMD:

YANG Yanyan, ZHANG Jie, FENG Suyang, QI Yue, LIU Xiaoqing, YU Xiaoyang, QU Xiaoshu. Electrochromic Composite Film and Device Based on Vanadium Tungstate and Congo Red[J]. Chem. J. Chinese Universities, 2020, 41(9): 1975.

Figures/Tables 11

References 30

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Film	ΔT(%)	t_c/s	t_b/s	CE/(cm²·C^?1)	Reference
[PEI/PSS/PEI/(P₂W₁₇V/NR)₂₀]	14.68	6.63	3.26	222	[25]
[PEI/PW₁₂/NR/PSS]₂₀	6.0	14.6	16.9	14.6	[28]
[PEI/P₅W₃₀/PEI/AR]₂₀	33.7	2.7	1.5	52	[29]
[PEI/P₂W₁₅V₃/PEI/CR]₂₀	22.55	2.02	12.67	122.67	This work

Film	ΔT(%)	t_c/s	t_b/s	CE/(cm²·C^?1)	Reference
[PEI/PSS/PEI/(P₂W₁₇V/NR)₂₀]	14.68	6.63	3.26	222	[25]
[PEI/PW₁₂/NR/PSS]₂₀	6.0	14.6	16.9	14.6	[28]
[PEI/P₅W₃₀/PEI/AR]₂₀	33.7	2.7	1.5	52	[29]
[PEI/P₂W₁₅V₃/PEI/CR]₂₀	22.55	2.02	12.67	122.67	This work