Preparation and Characterization of Pyrrole-(3,4-ethylenedioxythiophene) Copolymer Ordered Nanoarray Film†

doi:10.7503/cjcu20180312

Abstract

Abstract:

We adopted the anodic aluminum oxide(AAO) template electrochemical deposition method for synthesis of a new type of copolymer nano array membrane structure as lithium ion battery electrode material. This pyrrole-(3,4-ethylenedioxythiophene)(PE) copolymer nano-array membrane material has a lot of advantages, such as better electrochemical properties. The specific capacity can reach 1426.1 mA·h/g(the charge and discharge current density is 100 mA/g) and good cyclic stability(after 300 cycles of charging and discharging, the specific capacity remains above 1400 mA·h/g). Therefore, this multi-component polymer nanowire array may be widely developed for the next generation of long life, high-performance lithium-ion battery electrode materials.

Key words: Copolymer, Nano array, Electrochemical performance

CLC Number:

O631
R783

TrendMD:

QIAN Ming,XU Zhimin,LIU Weiwei,HAN Bing. Preparation and Characterization of Pyrrole-(3,4-ethylenedioxythiophene) Copolymer Ordered Nanoarray Film^†[J]. Chem. J. Chinese Universities, 2019, 40(3): 612.

Figures/Tables 5

Scheme 1 Preparation of PE nanowire array film materials

Fig.1 SEM images of PE nano array membrane from lateral(A), PE nano array membrane from positive(B), single PE array line(C) and TEM image of single PE array line(D)

Fig.2 EDS elemental analysis of PE array line(A) and carbon(B), nitrogen(C),oxygen(D) and sulphur(E)

Fig.3 Specific capacity-voltage curves of PE(A), PPy(B), PEDOT(C) and discharge rate of three materials(D)

Fig.4 Discharge ratio curves of PE(a), PPy(b) and PEDOT(c)

References 28

[1]	Dong X. L., Chen L., Liu J. Y., Haller S., Wang Y. G., Xia Y. Y., Science Advances, 2016, 2(1), e1501038
[2]	Manthiram A., Yu X. W., Wang S. F., Nature Reviews Materials, 2017, 2(4), 16103
[3]	Bachman J. C., Muy S., Grimaud A., Chang H. H., Pour N., Lux S. F., Paschos O., Maglia F., Lupart S., Lamp P., Giordano L., Yang S. H., Chem. Rev., 2016, 116(1), 140—162
[4]	Rong J. P., Masarapu C., Ni J., Zhang Z. J., Wei B. Q., ACS Nano, 2010, 4(8), 4683—4690
[5]	Liu J. Y., Zheng Q. Y., Goodman M. D., Zhu H. Y., Kim J., Krueger N. A., Ning H. L., Huang X. J., Liu J. H., Terrones M., Braun P. V., Adv. Mater., 2016, 28(35), 7696—7702
[6]	Xue Y. H., Ding Y., Niu J. B., Xia Z. H., Roy A., Chen H., Qu J., Wang Z. L., Dai L. M., Sci. Adv., 2015, 1(8), e1400198
[7]	Zhou G. M., Paek E., Hwang G. S., Manthiram A., Advanced Energy Materials, 2016, 6(2), 1501355
[8]	Chen N., Chen S. H., Ouyang C. B., Yu Y. W., Liu T. F., Li Y. J., Liu H. B., Li Y. L., NPG Asia Materials, 2013, 5, e59
[9]	Chen N., Xue Z., Yang H., Zhang Z., Gao J., Li Y. J., Liu H. B., Phys. Chem. Chem. Phys., 2015, 17(3), 1785—1789
[10]	Koski J. V., Kutvonen A., Khaymovich I. M., Ala-Nissila T., Pekola J. P., Phys. Rev. Lett., 2015, 115(26), e260602
[11]	Chen Y. B., Zhang J., ACC. Chem. Res., 2014, 47(8), 2273—2281
[12]	Zhang X. J., Shao Z. B., Zhang X. H., He Y. Y., Jie J. S., Adv. Mater., 2016, 28(47), 10409—10442
[13]	Liu J. W., Liang H. W., Yu S. H., Chem. Rev., 2012, 112(8), 4770—4799
[14]	Liu J., Xu X. J., Hu R. Z., Yang L. C., Zhu M., Advanced Energy Materials, 2016, 6(13), 1600256
[15]	Liu R. Q., Li D. Y., Wang C., Li N., Li Q., Lü X. J., Spendelow J. S., Wu G., Nano Energy, 2014, 6, 73—81
[16]	Du F. H., Li B., Fu W., Xiong Y. J., Wang K. X., Chen J. S., Advanced Energy Materials, 2014, 26(35), 6145—6150
[17]	Han F., Li D., Li W. C., Lei C., Sun Q., Lu A. H., Advanced Functional Materials, 2013, 23(13), 1692—1700
[18]	Tu L. L., Jia C. Y., Progress in Chemistry, 2010, 22(8), 1610—1618
	(涂亮亮, 贾春阳. 化学进展, 2010, 22(8), 1610—1618)
[19]	Liu J., Wang X. J., Li D. Y., Coates N. E., Segalman R. A., Cahill D. G., Macromolecules, 2015, 48(3), 585—591
[20]	Zheng H. J., Jiang Y. D., Xu J. H., Yang Y. J., Chem. J. Chinese Universities, 2010, 31(8), 1665—1670
	(郑华靖, 蒋亚东, 徐建华, 杨亚杰. 高等学校化学学报, 2010, 31(8), 1665—1670)
[21]	Li J., Zhang G. F., Chen N., Nie X. W., Ji B. X., Qu L. T., ACS Appl. Mater. Interfaces, 2017, 9(29), 24840—24845
[22]	Chen N., Qian X.M.., Lin H. W., Liu H. B., Li Y. L.,J. Mater. Chem., 2012, 22(22), 11068—11072
[23]	Qian M., Chen N., Liu M., Cheng L., Li J., Wang M., J. Solid State Electrochem., 2017, 21(11), 3121—3127
[24]	Zheng F. C., Yang Y., Chen Q. W., Nat. Commun., 2014, 5, doi:10.1038/ncomms6261
[25]	Ito Y., Cong W. T., Fujita T., Tang Z., Chen M. W., Angew. Chem. Int. Ed., 2015, 54(7), 2131—2136
[26]	Duan X. G., O' Donnell K., Sun H. Q., Wang Y. X., Wang S. B., Small, 2015, 11(25), 3036—3044
[27]	Dong L. Y., Hu C. G., Huang X. K., Chen N., Qu L. T., Chem-Asian J., 2015, 10(12), 2608—2613
[28]	Dong L. Y., Hu C. G., Song L., Huang X. K. , Chen N. , Qu L. T., Adv. Funct. Mater., 2016, 26(9), 1470—1476