Chem. J. Chinese Universities ›› 2016, Vol. 37 ›› Issue (10): 1907.doi: 10.7503/cjcu20160400
• Polymer Chemistry • Previous Articles Next Articles
YAO Jian, WANG Jianping*(), WEI Yao, WANG Xuechen, LI Wei, ZHANG Xingxiang
Received:
2016-06-02
Online:
2016-10-10
Published:
2016-09-20
Contact:
WANG Jianping
E-mail:jpwangcn@gmail.com
Supported by:
CLC Number:
TrendMD:
YAO Jian, WANG Jianping, WEI Yao, WANG Xuechen, LI Wei, ZHANG Xingxiang. Synthesis and Characterization of Polyprrole Microcapcule Containing ZnCl2 Solution†[J]. Chem. J. Chinese Universities, 2016, 37(10): 1907.
Sample | mBPO/g | Mass fraction of the monomer(%) | Concentration(%) | mTsOH/g | Mass fraction of TSOH(%) | mEmulsifier/g | |
---|---|---|---|---|---|---|---|
S1 | 6 | 123.71 | 0.1 | 1 | 2.0 | ||
S2 | 6 | 123.71 | 0.5 | 5 | 2.0 | ||
S3 | 6 | 123.71 | 1 | 10 | 2.0 | ||
S4 | 6 | 123.71 | 2 | 20 | 2.5 | ||
S5 | 6 | 123.71 | 3 | 30 | 3.0 | ||
S6 | 1 | 20.61 | 2 | 20 | 2.5 | ||
S7 | 4 | 82.47 | 2 | 20 | 2.5 | ||
S8 | 8 | 164.95 | 2 | 20 | 2.5 | ||
S9 | 6 | 123.71 | 2 | 20 | 0.05 | 1.03 | 2.5 |
S10 | 6 | 123.71 | 2 | 20 | 0.10 | 2.06 | 2.5 |
S11 | 6 | 123.71 | 2 | 20 | 0.20 | 4.12 | 2.5 |
S12 | 6 | 123.71 | 2 | 20 | 0.30 | 6.18 | 2.5 |
Table 1 Recipes for the fabrication of microcapsules
Sample | mBPO/g | Mass fraction of the monomer(%) | Concentration(%) | mTsOH/g | Mass fraction of TSOH(%) | mEmulsifier/g | |
---|---|---|---|---|---|---|---|
S1 | 6 | 123.71 | 0.1 | 1 | 2.0 | ||
S2 | 6 | 123.71 | 0.5 | 5 | 2.0 | ||
S3 | 6 | 123.71 | 1 | 10 | 2.0 | ||
S4 | 6 | 123.71 | 2 | 20 | 2.5 | ||
S5 | 6 | 123.71 | 3 | 30 | 3.0 | ||
S6 | 1 | 20.61 | 2 | 20 | 2.5 | ||
S7 | 4 | 82.47 | 2 | 20 | 2.5 | ||
S8 | 8 | 164.95 | 2 | 20 | 2.5 | ||
S9 | 6 | 123.71 | 2 | 20 | 0.05 | 1.03 | 2.5 |
S10 | 6 | 123.71 | 2 | 20 | 0.10 | 2.06 | 2.5 |
S11 | 6 | 123.71 | 2 | 20 | 0.20 | 4.12 | 2.5 |
S12 | 6 | 123.71 | 2 | 20 | 0.30 | 6.18 | 2.5 |
Fig.2 Optical microscope images of microcapsules with different concentrations of ZnCl2 Mass fraction of ZnCl2: (A) 1%; (B) 5%; (C) 10%; (D) 20%; (E) 30%.
Fig.5 Optical microscope images of microcapsules with different contents of BPOMass fraction of BPO: (A) 20.61%; (B) 82.47%; (C) 123.71%; (D) 164.95%.
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