Chem. J. Chinese Universities ›› 2014, Vol. 35 ›› Issue (11): 2410.doi: 10.7503/cjcu20140476
• Physical Chemistry • Previous Articles Next Articles
WANG Zitao, XIAO Changfa*(), ZHAO Jian, HU Xiao, XU Naiku
Received:
2014-05-21
Online:
2014-11-10
Published:
2014-10-09
Contact:
XIAO Changfa
E-mail:cfxiao@tjpu.edu.cn
Supported by:
CLC Number:
TrendMD:
WANG Zitao, XIAO Changfa, ZHAO Jian, HU Xiao, XU Naiku. Preparation of Reduced Graphene Oxide-based Melamine Sponge and Its Absorption Properties†[J]. Chem. J. Chinese Universities, 2014, 35(11): 2410.
Sorbent | Oil | Q/(g·g-1) | Ref. | Sorbent | Oil | Q/(g·g-1) | Ref. |
---|---|---|---|---|---|---|---|
RGOME | Toluene | 69.8 | This paper | Polypropylene nonwoven | Diesel | <8 | [ |
Trichloroethylene | 127.0 | This paper | Copolymerization of methyl | Toluene | <9 | [ | |
Kerosene | 59.3 | This paper | acrylate fiber | Trichloroethylene | <21 | [ | |
Cotton grass fiber | Gasoline | 20 | [ | Exfoliate graphite | Heavy oil | 75 | [ |
Corn stalk | Gasoline | 8 | [ | Carbon aerogel | Toluene | 130 | [ |
Modified PU foam | Toluene | 62 | [ | Chloroform | 110 | [ | |
Kerosene | 47 | [ | Spongy graphene | Toluene | 55 | [ | |
Polypropylene nonwoven | Toluene | <8 | [ | Kerosene | 45 | [ |
Table 1 Comparison of the adsorption capacity of various materials
Sorbent | Oil | Q/(g·g-1) | Ref. | Sorbent | Oil | Q/(g·g-1) | Ref. |
---|---|---|---|---|---|---|---|
RGOME | Toluene | 69.8 | This paper | Polypropylene nonwoven | Diesel | <8 | [ |
Trichloroethylene | 127.0 | This paper | Copolymerization of methyl | Toluene | <9 | [ | |
Kerosene | 59.3 | This paper | acrylate fiber | Trichloroethylene | <21 | [ | |
Cotton grass fiber | Gasoline | 20 | [ | Exfoliate graphite | Heavy oil | 75 | [ |
Corn stalk | Gasoline | 8 | [ | Carbon aerogel | Toluene | 130 | [ |
Modified PU foam | Toluene | 62 | [ | Chloroform | 110 | [ | |
Kerosene | 47 | [ | Spongy graphene | Toluene | 55 | [ | |
Polypropylene nonwoven | Toluene | <8 | [ | Kerosene | 45 | [ |
Fig.5 Three kinetic plots for the adsorption of RGOME in toluene(A) and kerosene(B) a. Pseudo-first-order kinetic equation; b. Pseudo-second-order kinetic equation; c. Bangham equation.
Oil | Pseudo-first-order kinetic equation | Pseudo-second-order kinetic equation | Bangham equation | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Qe/(g·g-1) | K1/s-1 | R2 | Qe/(g·g-1) | K2/s-1 | R2 | Qe/(g·g-1) | K3/s-1 | z | R2 | |
Toluene | 68.42 | 0.3726 | 0.9880 | 72.93 | 0.0089 | 0.9966 | 69.86 | 0.5304 | 0.6853 | 0.9980 |
Kerosene | 53.24 | 0.3140 | 0.9929 | 57.00 | 0.0092 | 0.9824 | 53.66 | 0.3820 | 0.8475 | 0.9955 |
Table 2 Parameters of three kinetic plots for the adsorption of RGOME in toluene and kerosene
Oil | Pseudo-first-order kinetic equation | Pseudo-second-order kinetic equation | Bangham equation | |||||||
---|---|---|---|---|---|---|---|---|---|---|
Qe/(g·g-1) | K1/s-1 | R2 | Qe/(g·g-1) | K2/s-1 | R2 | Qe/(g·g-1) | K3/s-1 | z | R2 | |
Toluene | 68.42 | 0.3726 | 0.9880 | 72.93 | 0.0089 | 0.9966 | 69.86 | 0.5304 | 0.6853 | 0.9980 |
Kerosene | 53.24 | 0.3140 | 0.9929 | 57.00 | 0.0092 | 0.9824 | 53.66 | 0.3820 | 0.8475 | 0.9955 |
Oil | Qe(Theoretical value)/(g·g-1) | Qe(Experiment value)/(g·g-1) | Relative error(%) |
---|---|---|---|
Toluene | 68.42 | 69.77 | 1.9 |
Kerosene | 53.24 | 53.82 | 1.0 |
Table 3 Comparison of Qe of RGOME between the theoretical value and experiment value
Oil | Qe(Theoretical value)/(g·g-1) | Qe(Experiment value)/(g·g-1) | Relative error(%) |
---|---|---|---|
Toluene | 68.42 | 69.77 | 1.9 |
Kerosene | 53.24 | 53.82 | 1.0 |
Fig.6 Effect of adsorption time on toluene concentration of mixed system composed of toluene and water(A), adsorption capacity of RGOME(B) and adsorption efficiency of RGOME(C)
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