Solvent-directing Supramolecular Assemblies of Mn4-thiacalix[4]arene

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 2175.

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Solvent-directing Supramolecular Assemblies of Mn4-thiacalix[4]arene

BI Yan-Feng, LIAO Wu-Ping

State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2011-05-03 Revised:2011-08-05 Online:2011-09-10 Published:2011-08-15
Contact: LIAO Wu-Ping E-mail:wpliao@ciac.jl.cn
Supported by:
国家自然科学基金(批准号: 20971119)资助.

Abstract

Abstract:

Two tetranuclear compounds, Mn4(T4A)2 (1) and Mn4(T4A)2 (DMF)2(2) (T4A = thiacalix[4]arene), were synthesized via the solvothermal reaction of manganese (II) acetic and thiacalix[4]arene with different solvents. Single-crystal analysis reveals that compound 1 with a two-dimensional Kagomé lattice was obtained with the mixed CHCl3/CH3OH solvent, while the interpenetrated 2D compound 2 was synthesized in the mixed DMF/CH3OH solution. Porous compound 1 has some large solvent accessible voids while compound 2 has an impacted extended structure.

Key words: Calixarene, Metal cluster, Inductive effect, Supramolecular assembly

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BI Yan-Feng, LIAO Wu-Ping. Solvent-directing Supramolecular Assemblies of Mn4-thiacalix[4]arene[J]. Chem. J. Chinese Universities, 2011, 32(9): 2175.

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Solvent-directing Supramolecular Assemblies of Mn4-thiacalix[4]arene

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