Study on Nanometer Hybrid Low Dielectric Constant Materials from Polyhedral Oligosilsesquioixanes

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 1962.

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Study on Nanometer Hybrid Low Dielectric Constant Materials from Polyhedral Oligosilsesquioixanes

XU Hong-Yao*, YAN Zheng-Quan, ZHANG Chao, SU Xin-Yan, GUANG Shan-Yi

State Key Laboratory for Modification of Chemical Fibers and Polymeric Materials, College of Material Science and Engineering, Donghua University, Shanghai 201620, China

Received:2011-04-11 Revised:2011-04-27 Online:2011-09-10 Published:2011-08-11
Contact: XU Hong-Yao E-mail:hongyaoxu@dhu.edu.cn
Supported by:
国家自然科学基金(批准号: 51073031, 51003013, 20971021和20974018)资助.

Abstract

Abstract: Polyhedral oligosilsesquioixanes (POSS) is a nanosized organic-inorganic hybrid molecule, which consists of a well-defined cage-like nano inorganic core [(SiO1.5)n] surrounded by organic corner groups. The unique structure of POSS molecules provide a an important platform for controllably preparation of hybrid nanocomposites in molecular level dispersion. In this paper, the influence of hybrid molecular structure on properties and forming mechanism of low dielectric constant, in particular, the research progress of POSS-based nanocomposite low dielectric constant materials were summarized.

Key words: Polyhedral oligomeric silsesquioxane(POSS), Nanocomposite, Low dielectric constant

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XU Hong-Yao*, YAN Zheng-Quan, ZHANG Chao, SU Xin-Yan, GUANG Shan-Yi . Study on Nanometer Hybrid Low Dielectric Constant Materials from Polyhedral Oligosilsesquioixanes[J]. Chem. J. Chinese Universities, 2011, 32(9): 1962.

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Study on Nanometer Hybrid Low Dielectric Constant Materials from Polyhedral Oligosilsesquioixanes

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