Progress in Synthesis of Cycloaramides and Self-assembly Behavior

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (9): 1950.

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Progress in Synthesis of Cycloaramides and Self-assembly Behavior

YANG Yong-An, FENG Wen, YUAN Li-Hua*

Key Laboratory for Radiation Physics and Technology, Ministry of Education, Institute of Nuclear Science and Technology, College of Chemistry, Sichuan University, Chengdu 610064, China

Received:2011-04-13 Revised:2011-07-07 Online:2011-09-10 Published:2011-08-11
Contact: YUAN Li-Hua E-mail:lhyuan@scu.edu.cn
Supported by:
国家自然科学基金(批准号: 20774059, 20672078)和教育部博士学科点基金(批准号: 20090181110047)资助.

Abstract

Abstract: In this review we summarize the recent progress in synthesis of cycloaramides assisted by three-center hydrogen bonding and the remote steric effect, and their self-assembly behaviors of these macrocycles. The strategies for preparing shape-persistent aromatic oligoamide macrocycles with different cavity sizes are discussed based on the highly efficient, one-step macrocyclization. The self-assembly properties of these cycles can be manipulated by means of altering side chains on the periphery. A brief account of cycloaramides with some applications is also given.

Key words: Cycloaramide, Shape-persistent macrocycle, Three-center hydrogen bond, Self-assembly

CLC Number:

0625

TrendMD:

YANG Yong-An, FENG Wen, YUAN Li-Hua*. Progress in Synthesis of Cycloaramides and Self-assembly Behavior[J]. Chem. J. Chinese Universities, 2011, 32(9): 1950.

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Progress in Synthesis of Cycloaramides and Self-assembly Behavior

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