Template-directed Synthesis of a Novel Oxalate Compound [Co(dien)2][NaCo2(C2O4)4] Using Co(Ⅲ) Complex as Template

Chem. J. Chinese Universities ›› 2011, Vol. 32 ›› Issue (3): 527.

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Template-directed Synthesis of a Novel Oxalate Compound [Co(dien)2][NaCo2(C2O4)4] Using Co(Ⅲ) Complex as Template

PAN Qin-He^1*, CHEN Qiang², HAN Yi-De³, HU Tong-Liang^2*, BU Xian-He²

1. Department of Materials and Chemical Engineering, Ministry of Education Key Laboratory of Application Technology of Hainan Superior Resources Chemical Materials, Hainan University, Haikou 570228, China;
2. Department of Chemistry, Tianjin Key Laboratory of Metal & Molecule\|based Material Chemistry, Nankai University, Tianjin 300071, China;
3. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, China

Received:2010-10-18 Revised:2010-12-27 Online:2011-03-10 Published:2011-02-23
Contact: PAN Qin-He;HU Tong-Liang E-mail:panqinhe@163.com; tlhu@nankai.edu.cn
Supported by:
国家自然科学基金(批准号: 20801029, 51073079)、天津市自然科学基金(批准号: 10JCZD JC22100)和海南大学科研启动基金(批准号: kyqd1051)资助.

Abstract

Abstract: By using Co(dien)2?Cl3 as the template, a novel oxalate compound [Co(dien)2][NaCo2(C2O4)4]?H2O has been synthesized under hydrothermal conditional. Its structure is determined by single-crystal X-ray diffraction analysis, elemental analyses, ICP, and X-ray powder diffraction. It crystallizes in monoclinic, space group C2/c with a = 1.3805(3) nm, b = 1.3017(3) nm, c = 1.5913(3) nm, β = 104.41(3)°, V = 2.7695(10) nm3, Z = 8. In this structure, the Co2+ cations are first linked to oxalate ligands to form a familiar chain-like building unit [Co(C2O4)2]n2n-, and then those chain-like building units are further connected by Na+ cations, which are dispersed between the chains, to construct a three dimensional oxalate open-framework of [NaCo2(C2O4)4]n3n-. The complex cations Co(dien)23+ are encapsulated inside the channels as template.

Key words: Oxalate, Metal complex, Hydrothermal synthesis, Host-guest system

CLC Number:

O614

TrendMD:

PAN Qin-He*, CHEN Qiang, HAN Yi-De, HU Tong-Liang*, BU Xian-He. Template-directed Synthesis of a Novel Oxalate Compound [Co(dien)2][NaCo2(C2O4)4] Using Co(Ⅲ) Complex as Template[J]. Chem. J. Chinese Universities, 2011, 32(3): 527.

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Template-directed Synthesis of a Novel Oxalate Compound [Co(dien)2][NaCo2(C2O4)4] Using Co(Ⅲ) Complex as Template

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