Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts

Chem. J. Chinese Universities ›› 2010, Vol. 31 ›› Issue (8): 1643.

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Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts

MOU Li^1*, QU Xue-Jian², WANG Chun-Yan³

1. School of Bioscience and Technology of Changchun University, Changchun 130023, China;
2. College of Chemistry,
3. School of Public Health, Jilin University, Changchun 130012, China

Received:2009-11-16 Online:2010-08-10 Published:2010-08-10
Contact: MOU Li. E-mail: limu1970@163.com
Supported by:
石油化工催化材料与反应工程国家重点实验室(中国石油化工股份有限公司石油化工科学研究院)开放基金课题资助.

Abstract

Abstract: A novel ordered mesoporous solid acid catalyst(FDU-16-SO3H) was prepared by sulfonation of mesoporous polymers(FDU-16). The sample was carefully investigated by XRD, N2 adsorption, TEM and IR. Characterization results suggested that the mesostructure of the sample was retained during the sulfonation. Catalytic esterification and acylation over FDU-16-SO3H show high catalytic activities, which is attributed the strong acidity, mesoporous structure and hydrophobic framework. Excellent catalytic properties ensure such mesoporous solid acid great potential application in industry.

Key words: Solid acid catalyst, Ordered mesopores, Phenol-formaldehyde resins, Esterification, Acylation

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MOU Li*, QU Xue-Jian, WANG Chun-Yan. Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts[J]. Chem. J. Chinese Universities, 2010, 31(8): 1643.

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Synthesis and Catalytic Properties of Ordered Mesoporous Phenol-Formaldehyde Resins as Solid Acid Catalysts

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