Synthesis and SERS Properties of Flowerlike Ag Micro-nano Structures

Abstract

Abstract: Novel nanoplate-composed flowerlike Ag micro-nano structures were fabricated by a simple aqueous solution route. The products were characterized by X-ray diffraction(XRD), scanning electronic microscopy(SEM), transmission electron microscopy(TEM), high resolution transmission electron microscopy(HRTEM), and selected area electrical diffraction(SAED). The effect of pH on the morphology of the products was investigated and the mechanisms of the formation of the flowerlike Ag micro-nano structures were discussed preliminarily. The products were composed of a great deal of interlaced nanoplates, experiments indicated that these micro-nano structures have very strong SERS activity as SERS substrates.

Key words: Surface-enhanced Raman scattering, Hierarchy structure, Silver

TrendMD:

ZHANG Bo, ZHAO Ai-Wu*, WANG Da-Peng , GUO Hong-Yan, LI Da, LI Ming. Synthesis and SERS Properties of Flowerlike Ag Micro-nano Structures[J]. Chem. J. Chinese Universities, 2010, 31(8): 1491.

References

[1]HU Jia-Wen(胡家文), ZHAO Bing(赵冰), XU Wei-Qing(徐蔚青), XIE Yu-Tao(谢玉涛), FAN Yu-Guo(樊玉国), LI Bo-Fu(李伯符), WANG Hua(王华). Chem. J. Chinese Universities(高等学校化学学报)[J], 2002, 23(1): 123—125 [2]Nabika H., Deki S.. J. Phys. Chem. B[J], 2003, 107(35): 9161—9164 [3]Alivisatos A. P.. J. Phys. Chem.[J], 1996, 100(31): 13226—13239 [4]ZHANG Yu-Min(张玉敏), LIU Hai-Yan(刘海燕), SONG Wen-Bo(宋文波). Chem. J. Chinese Universities(高等学校化学学报)[J], 2010, 31(1): 157—161 [5]Yang Y., Matsubara S., Xiong L., Hayakawa T., Nogami M.. J. Phys. Chem. C[J], 2007, 111(26): 9095—9104 [6]NING Xiao-Hua(宁晓华), XU Shu-Ping(徐抒平), DONG Feng-Xia(董凤霞), AN Jing(安静), TANG Bin(唐彬), ZHOU Ji(周吉), XU Wei-Qing(徐蔚青). Chem. J. Chinese Universities(高等学校化学学报) [J], 2009, 30(1): 159—163 [7]Sun Y., Xia Y.. Science[J], 2002, 298(5601): 2176—2179 [8]Zhou J., An J., Tang B., Xu S. P., Cao Y. X., Zhao B., Xu W. Q., Chang J. J., Lomardi J. R.. Langmuir[J], 2008, 24(18): 10407—10413 [9]Sun Y., Mayers B., Herricks T., Xia Y.. Nano Lett.[J], 2003, 3(7): 955—960 [10]Hao E., Bailey R. C., Schatz G. C., Hupp J. T., Li S.. Nano Lett.[J], 2004, 4(2): 327—330 [11]Liang H., Li Z., Wang W., Wu Y., Xu H.. Adv. Mater.[J], 2009, 21(45): 4614—4618 [12]Lu L., Kobayashi A., Tawa K., Ozaki Y.. Chem. Mater.[J], 2006, 18(20): 4894—4901 [13]WANG Lian-Ying(王连英), JI Xiao-Hui(纪小会), ZHANG Xin-Tong(张昕彤), BAI Yu-Bai(白玉白), LI Tie-Jin(李铁津), ZHI Zhuang-Zhi(支壮志), KONG Xiang-Gui(孔祥贵), LIU Yi-Chun(刘益春). Chem. J. Chinese Universities(高等学校化学学报)[J], 2002, 23(11): 2169—2171 [14]Yabu H., Hirai Y., Matsuo Y., Ijiro K., Shimomura M.. Chemical Communications[J], 2010, 46(17): 2298—2300 [15]LI Xiao-Ling(李小灵), XU Wei-Qing(徐蔚青), ZHANG Jun-Hu(张俊虎), JIA Hui-Ying(贾慧颖), ZHAO Bing(赵冰), YANG Bai(杨柏). Chem. J. Chinese Universities(高等学校化学学报)[J], 2003, 24(4): 707—710 [16]Mulvihill M. J., Ling X. Y., Henzie J., Yang P.. J. Am. Chem. Soc.[J], 2010, 132(1): 268—274 [17]Jin R. C., Cao Y. C., Hao E. C., Metraux G. S., Schatz G. C., Mirkin C. A.. Nature[J], 2003, 425(6957): 487—490 [18]Jin R. C., Cao Y. W., Mirkin C. A., Kelly K. L., Schatz G. C., Zheng J. G.. Science[J], 2001, 294(5548): 1901—1903 [19]Chen S. H., Carroll D. L.. Nano Lett.[J], 2002, 2(9): 1003—1007 [20]Hao E., Kelly K. L., Hupp J. T., Schatz G. C.. J. Am. Chem. Soc.[J], 2002, 124(51): 15182—15183 [21]Maillard M., Giorgio S., Pileni M. P.. Adv. Mater.[J], 2002, 14(15): 1084—1096 [22]Pastoriza-Santos I., Liz-Marzan L. M.. Nano Lett.[J], 2002, 2(8): 903—905 [23]Wang Z. L.. J. Phys. Chem. B[J], 2000, 104(6): 1153—1175 [24]Germain V., Li J., Ingert D., Wang Z. L., Pileni M. P.. J. Phys. Chem. B[J], 2003, 107(34): 8717—8720 [25]Xiong Y., McLellan J. M., Chen J., Yin Y., Li Z. Y., Xia Y.. J. Am. Chem. Soc.[J], 2005, 127(48): 17118—17127 [26]Xiong Y., Washio I., Chen J., Cai H., Li Z. Y., Xia Y. N.. Langmuir[J], 2006, 22(20): 8563—8570 [27]Washio I., Xiong Y., Yin Y., Xia Y.. Adv. Mater.[J], 2006, 18(13): 1745—1749 [28]Cleveland C. L., Landman U.. J. Chem. Phys.[J], 1991, 94(11): 7376—7396 [29]Liu S., Liu W., Zuo J., Li Y. Z., You X. Z.. Inorg. Chem. Commun.[J], 2005, 8(3): 328—330 [30]Henglein A., Giersig M.. J. Phys. Chem. B[J], 1999, 103(44): 9533—9539 [31]Watanable H., Hayazawa N., Inouye Y., Kawata S.. J. Phys. Chem. B[J], 2005, 109(11): 5012—5020 [32]Deng S., Fan H. M., Zhang X., Loh P. K., Cheng C. L., Sow C. H., Foo Y. L.. Nanotechnology[J], 2009, 20(17): 175705-1—175705-7 [33]Kottmann J. P., Martin O. J. F., Smith D. R., Schultz S.. Phys. Rev. B[J], 2001, 64(23): 235402-1—235402-10 [34]Fang J. X., Yi Y., Ding B. J., Song X. P.. Appl. Phys. Lett.[J], 2008, 92(13): 131115—131117

Related Articles 15

[1]	LI Yulong, XIE Fating, GUAN Yan, LIU Jiali, ZHANG Guiqun, YAO Chao, YANG Tong, YANG Yunhui, HU Rong. A Ratiometric Electrochemical Sensor Based on Silver Ion Interaction with DNA for the Detection of Silver Ion [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220202.
[2]	WANG Junyang, LIU Zheng, ZHANG Qian, SUN Chunyan, LI Hongxia. Application of DNA Silver Nanoclusters in the Fluorescence Biosensors based on Functional Nucleic Acids [J]. Chem. J. Chinese Universities, 2022, 43(6): 20220010.
[3]	YANG Zhaohua, CHENG Hongjing, YANG Yi, LIU Hui, DU Feipeng, ZHANG Yunfei. Preparation of Silver-loaded Polyvinyl Alcohol Sponge and Its Interfacial Photothermal Driven Water Evaporation Performance [J]. Chem. J. Chinese Universities, 2022, 43(10): 20220181.
[4]	CHEN Shaoyun, ZHANG Xingying, LIU Ben, TIAN Du, LI Qi, CHEN Fang, HU Chenglong, CHEN Jian. Controllable Growth of Silver Nanoparticles on TiO₂ Tetragonal Prism Nanarrays and Its SERS Effect [J]. Chem. J. Chinese Universities, 2021, 42(8): 2381.
[5]	CHEN Feng, CHENG Na, ZHAO Jianwei, SONG Yitian, SUN Yanyan, LOU Xinli, TONG Xiayan. Electrodeposition Mechanism and Surface-enhanced Raman Spectroscopic Effect of Nano-sized Silver Layer [J]. Chem. J. Chinese Universities, 2021, 42(6): 1891.
[6]	LI Qi, TIAN Du, CHEN Shaoyun, ZHONG Min, HU Chenglong, CHEN Jian. Controllable Assembling of Silver Nanosheets on Non-woven Fabric Fibers and Its SERS Effect [J]. Chem. J. Chinese Universities, 2021, 42(3): 736.
[7]	YANG Xinjie, LAI Yanqiong, LI Qiuyang, ZHANG Yanli, WANG Hongbin, PANG Pengfei, YANG Wenrong. An Enzyme-free and Label-free Fluorescent Probe for Detection of Microcystin-LR Based on Circular DNA-Silver Nanoclusters [J]. Chem. J. Chinese Universities, 2021, 42(12): 3600.
[8]	WANG Bodong, PAN Meichen, ZHUO Ying. Construction of Electrochemiluminescence Sensing Interface Based on Silver Nanoclusters-Silica Nanoparticles and Biomolecular Recognition [J]. Chem. J. Chinese Universities, 2021, 42(11): 3519.
[9]	ZHANG Mengyao, YU Renpeng, HAN Mei, LIU Jianfang, LI Moxia, HU Jiawen, TIAN Zhongqun. Salt-Induced Self-assembly of Au Nanoparticles and Sedimentation Enables Plasmonic Black Au film with Broadband Absorption Properties [J]. Chem. J. Chinese Universities, 2020, 41(8): 1903.
[10]	LIU Zhaoyang, SONG Yongxin, WANG Tianshu, SHAN Guiye. Preparation of Histidine Modified Prussian Blue and Its Interaction with Silver Ions^† [J]. Chem. J. Chinese Universities, 2020, 41(7): 1492.
[11]	WEI Simin,WANG Yinghui,TANG Zhishu,SU Rui,HU Jinhang,GUO Hui,LI Chen,JIANG Jintao,SONG Zhongxing. Novel Biosynthesis Method of Silver Nanoparticle by UV Radiation of Cornus Officinalis Aqueous Extract and Biological Activities ^† [J]. Chem. J. Chinese Universities, 2020, 41(6): 1391.
[12]	XIAO Zhourui,HUANG Donghua,BIAN Mengmeng,YUAN Yali,NIE Jinfang. Fluorescence Detection Based on DNA-templated Silver Nanoclusters and the Construction of Multi-level Logic Gate ^† [J]. Chem. J. Chinese Universities, 2020, 41(1): 102.
[13]	FENG Wei,WANG Bowei,JIANG Yang,LI Longyun. Design, Preparation and Surface-enhanced Raman Scattering(SERS) Spectrum of Single Ag Nanodot^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1345.
[14]	QI Qi,LU Bingxin,CHE Yuping,WANG Yang,ZHAI Jin. Bimetallic Multi-core Nanoparticles with Dual SiO₂ Layer Au@SiO₂@Ag@SiO₂ for the Detection of Glucose^† [J]. Chem. J. Chinese Universities, 2019, 40(5): 887.
[15]	CHEN Yan,DONG Xuejiao,SHAN Guiye. Preparation of Liposome@Ag/Au Nanocomposites and Their Interaction with H₂ $O 2 †$ [J]. Chem. J. Chinese Universities, 2019, 40(4): 639.