Synthesis and Structure Characterization of (C6H8N3)+I3- and [(Cu3I4)(C8H17N2)] Based on in situ Ligand Reaction

Abstract

Abstract:

Two I-containing compounds, (C₆H₈N₃)⁺I₃^-(1, C₆H₇N₃=2,3-dihydroimidazo[1,2-a]pyrimidine-1-ium) and [(Cu₃I₄)(C₈H₁₇N₂)](2, C₈H₁₇N₂=N-ethyl-1,4-diazabicyclo[2.2.2]octane), were synthesized under solvothermal conditions based on in situ ligand reaction and characterized via elemental analysis, XRD and single crystal X-ray diffraction analysis. Complex 1 crystallizes in the triclinic system, space group P1 with a=0.74281(15) nm, b=0.84241(17) nm, c=0.9993(2) nm, α=82.02(3)°, β=83.30(3)°, γ=82.92(3)°, V=0.6114(2) nm³. Complex 2 crystallizes in the monoclinic system, space group P2₁/c with a=0.68924(14) nm, b=1.0786(2) nm, c=2.2779(5) nm, β=94.84(3)°, V=1.6874(6) nm³. Two kinds of in situ ligand reaction were found in the synthesis of these complexes. (C₆H₈N₃)⁺ ligand was synthesized from 2-aminopyrimidine and ethanol in complex 1, whereas(C₈H₁₇N₂)⁺ ligand was synthesized from 1,4-diazabicyclo[2.2.2]octane and ethanol in complex 2.

Key words: Crystal structure, Solvothermal reaction, In situ reaction, Copper iodide

TrendMD:

NING De-Kuan, BI Ming-Hui, LI Guang-Hua, LIU Guo-Zong, SHI Zhan*, FENG Shou-Hua. Synthesis and Structure Characterization of (C₆H₈N₃)⁺I₃^- and [(Cu₃I₄)(C₈H₁₇N₂)] Based on in situ Ligand Reaction[J]. Chem. J. Chinese Universities, 2009, 30(5): 845.

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Synthesis and Structure Characterization of (C₆H₈N₃)⁺I₃^- and [(Cu₃I₄)(C₈H₁₇N₂)] Based on in situ Ligand Reaction

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