Synthesis, Crystal Structure and Magnetic Property of a New Double Chainlike Heterobinuclear Supramolecular Architecture [Cu(oxbe)Ni(dpt)(H2O)]ClO4 ·0.5H2O

Chem. J. Chinese Universities

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Synthesis, Crystal Structure and Magnetic Property of a New Double Chainlike Heterobinuclear Supramolecular Architecture [Cu(oxbe)Ni(dpt)(H₂O)]ClO₄ ·0.5H₂O

LI Jian-Ding¹, ZHANG Wu¹, TAO Ruo-Jie¹*, WANG Qing-Lun², CHENG Yan-Xiang³

1. Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, China;
2. Department of Chemistry, Nankai University, Tianjin 300071, China;
3. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2007-07-30 Revised:1900-01-01 Online:2008-03-10 Published:2008-03-10
Contact: TAO Ruo-Jie

Abstract

Abstract: A new heterobinuclear complex bridged by N-benzoato-N'-(2-aminoethyl)oxamido trianion(oxbe) and end-capped with dipropylenetriamine(dpt), [Cu(oxbe)Ni(dpt)(H₂O)]ClO₄·0.5H₂O, was synthesized and characterized by elemental analyses and IR spectra. The crystal structure was determined by single-crystal X-ray diffraction analyses. There are hydrogen bonds in the complex resulting in the formation of the double chainlike supramolecular architecture. The variable temperature magnetic susceptibility measured at 5—300 K indicates the presence of a medial antiferromagnetic interaction through the oxamido bridge in binuclear system Cu(S_Cu=1/2)-Ni(S_Ni=1) with magnetic parameters J=-62.3 cm^-1, g=2.11.

Key words: Copper, Nickel, Double chainlike, Supramolecular architecture, Magnetic property

CLC Number:

O614

TrendMD:

LI Jian-Ding¹, ZHANG Wu¹, TAO Ruo-Jie¹*, WANG Qing-Lun², CHENG Yan-Xiang³. Synthesis, Crystal Structure and Magnetic Property of a New Double Chainlike Heterobinuclear Supramolecular Architecture [Cu(oxbe)Ni(dpt)(H₂O)]ClO₄ ·0.5H₂O[J]. Chem. J. Chinese Universities, doi: .

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Synthesis, Crystal Structure and Magnetic Property of a New Double Chainlike Heterobinuclear Supramolecular Architecture [Cu(oxbe)Ni(dpt)(H₂O)]ClO₄ ·0.5H₂O

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