Synthesis of Eight-arm Polystyrene by Atom Transfer Radical Polymerization

Chem. J. Chinese Universities

• 研究论文 • Previous Articles Next Articles

Synthesis of Eight-arm Polystyrene by Atom Transfer Radical Polymerization

YU Xi-Fei^1,2, ZHANG Guo¹, SHI Tong-Fei², AN Li-Jia²

1. College of Chemistry, Key Laboratory of Automobile Materials of Ministry of Education, Jilin University, Changchun 130023, China;
2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China

Received:2006-08-14 Revised:1900-01-01 Online:2006-12-10 Published:2006-12-10
Contact: AN Li-Jia

Abstract

Abstract: A new initiator for atom transfer radical polymerization(ATRP), (Cl₂HCCOOCH₂)₄C(TDCAP) was designed and successfully synthesized. The initiator was used to initiate the polymerization of styrene via ATRP to method yield an eight-arm polystyrene with functional end-group chlorides. The different polymers could be prepared via ATRP of different monomers at 130 ℃ using TDCAP/CuCl/bPy as the initiating system. The initiator and eight-armed polymer were characterized by means of ¹H NMR, FTIR and GPC.

Key words: Atom transfer radical polymerization, Eight-armed polymer, Polystyrene

CLC Number:

O631.5

TrendMD:

YU Xi-Fei^1,2, ZHANG Guo¹, SHI Tong-Fei², AN Li-Jia². Synthesis of Eight-arm Polystyrene by Atom Transfer Radical Polymerization[J]. Chem. J. Chinese Universities, doi: .

[1]	LI Wei, LUO Piao, HUANG Lianzhan, CUI Zhiming. Lithium Polystyrene Sulfonate Based Interfacial Protective Layer for Lithium Metal Anodes [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220166.
[2]	WANG Lin, ZHANG Yanhui, Arzugul Muslim, LAN Haidie. Morphology and Size Regulation of Polyaniline Induced by PS-b-P2VP as Template and Its Electrochemical Characters [J]. Chem. J. Chinese Universities, 2019, 40(8): 1748.
[3]	FENG Wei,WANG Bowei,JIANG Yang,LI Longyun. Design, Preparation and Surface-enhanced Raman Scattering(SERS) Spectrum of Single Ag Nanodot^† [J]. Chem. J. Chinese Universities, 2019, 40(7): 1345.
[4]	WU Shanshan,WEI Chanling,ZHAO Lijuan,TIAN Yang,WANG Xia,GONG Bolin. Preparation and Enrichment Properties of Novel Magnetic Restricted Access Media-molecularly Imprinted Composites^† [J]. Chem. J. Chinese Universities, 2019, 40(6): 1150.
[5]	XU Dan,DING Yadan,WANG Xue,CONG Tie,LIU Junping,HONG Xia,PAN Ying. Microdroplet Detection of Protein Based on Superhydrophobic Polystyrene Film^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1913.
[6]	FENG Wei,WANG Bowei,ZHENG Yan,JIANG Yang. Preparation and Surface-enhanced Raman Scattering(SERS) of Single Au Nanodot^† [J]. Chem. J. Chinese Universities, 2018, 39(9): 1875.
[7]	QIN Yanli, XU Haiping, QIU Houtian, ZHAI Yue, DAI Xiujuan, YANG Dandan, WANG Jingrong. Preparation and PTC Properties of HIPS/HDPE/CB Composites^† [J]. Chem. J. Chinese Universities, 2018, 39(6): 1305.
[8]	WANG Zhengzhou,YANG Ting. Preparation and Properties of Expanded Vermiculite Coated Expanded Polystyrene/Cement Composite Foams^† [J]. Chem. J. Chinese Universities, 2018, 39(5): 1098.
[9]	DENG Caisong, PAN Tingting, DU Lan, WANG Ming, NI Haibin, NI Xiaoqi. Fabrication of Monolayer Crystalline Films on Optical Fiber End by Micro-flow Injection Method^† [J]. Chem. J. Chinese Universities, 2018, 39(4): 708.
[10]	LI Aiju, WANG Yuxi, LU Shaoyong, LIU Kun. Ligand Exchange of Gold Nanoparticles with Thiol-terminated Polystyrene^† [J]. Chem. J. Chinese Universities, 2018, 39(3): 552.
[11]	LU Zhiwei, CHEN Shun, JU Yanyun, ZHANG Yang, XIONG Chuanxi, DONG Lijie. Synthesis and Properties of PS-b-P(DMS-stat-VMS) Block Copolymer [J]. Chem. J. Chinese Universities, 2017, 38(8): 1484.
[12]	LU Si, ZHANG Dingshengzi, LIU Bing, XU Hong, GU Hongchen. Preparation of High-Performance QD-encoded Magnetic Barcodes^† [J]. Chem. J. Chinese Universities, 2017, 38(4): 509.
[13]	ZHANG Jingjing, LI Li, HAO Yuting, SUN Leilei, ZHANG Xinyue. Preparation and Photocatalytic Hydrogen Evolution Performance of In₂O₃/ZrO₂-TiO₂ Hollow Spheres^† [J]. Chem. J. Chinese Universities, 2017, 38(2): 238.
[14]	SHEN Xiaohua, HU Jiawen. Synthesis of Polystyrene/silver Nanoparticels Composite Spheres and Their Catalytical Application^† [J]. Chem. J. Chinese Universities, 2017, 38(11): 2015.
[15]	YU Tian, XU Chengnan, YU Yuan, ZHAO Feifei, PAN Yiting, LIU Cai, HUANG Yongdong, ZHANG Rongyue. Preparation of Gigaporous Microspheres Through Atom Transfer Radical Polymerization^† [J]. Chem. J. Chinese Universities, 2016, 37(9): 1740.

Synthesis of Eight-arm Polystyrene by Atom Transfer Radical Polymerization

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments