Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface

Chem. J. Chinese Universities

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Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface

ZHAO Jian-Ying^1,2, MA Li¹, JIN Ri-Zhe¹, GAO Lian-Xun¹

1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;
2. Graduate School of Chinese Academy of Sciences, Beijing 100049, China

Received:2006-06-12 Revised:1900-01-01 Online:2006-12-10 Published:2006-12-10
Contact: GAO Lian-Xun

Abstract

Abstract: The 6-carboxaldehyde-2, 2'∶6',2"-terpyridine was synthesized and assembled on the aminosilanization quartz substrate by the Schiff base interfacial group. Then the substrate was reacted with ruthenium and 6-bromo-2,2'-bipyridine to form a new Schiff base type Ru complexes. The process of the complexes assembled was characterized by UV-Vis absorption spectra and XPS. The film exhibited photoluminescence arising from π*-t_2g ligand-to-metal transition of Ru complex. From the fluorescent spectra, we observed the behavior of Ru(Ⅱ) complexes is greatly affected by the schiff base ligand. The novel Schiff base ligand Ru(Ⅱ) complexes exhibited strong and pure luminescent intensity. It was different from the other type ruthenium complexes. The result shows that there are many ralations between the structure and the properties of the complex.

Key words: Self-assemble, Pyridine, Ru complex, Schiff base

CLC Number:

O629
O641.4

TrendMD:

ZHAO Jian-Ying^1,2, MA Li¹, JIN Ri-Zhe¹, GAO Lian-Xun¹. Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface

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