Synthesis and Characterization of a Novel Azo Compound with ‘Dumbbell Shape’

Chem. J. Chinese Universities

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Synthesis and Characterization of a Novel Azo Compound with ‘Dumbbell Shape’

MAO Hua-Ping¹, YU You-Hai¹, CHEN Liang¹, LU Xiao-Feng¹, ZHANG Wan-Jin¹, ZHANG Hong-Xing²

1. Alan G. MacDiarmid Institute, Jilin University, Changchun 130012, China;
2. Institute of Theoretical Chemistry, State Key Laboratory of Theoretical and Computational Chemistry, Jilin University, Changchun 130021, China

Received:2006-03-07 Revised:1900-01-01 Online:2006-10-10 Published:2006-10-10
Contact: ZHANG Wan-Jin

Abstract

Abstract: A novel azo compound with ‘dumbbell shape’ was synthesized successfully and characterized by MALDI-MS, FTIR, elemental analysis, ¹H NMR and ¹³C NMR. UV-Vis spectrum was used to monitor the trans-cis isomerization and theoretical calculations were used to modelize the trans and cis isomers. The trans and cis isomers of the ‘dumbbell shape’ azo compound are both stable at room temperature because of the large end group.

Key words: Azobenzene, Dumbbell, UV-Vis spectrum, cis-trans isomerization, Theoretical calculation

CLC Number:

O631
O625.65

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MAO Hua-Ping¹, YU You-Hai¹, CHEN Liang¹, LU Xiao-Feng¹, ZHANG Wan-Jin¹, ZHANG Hong-Xing². Synthesis and Characterization of a Novel Azo Compound with ‘Dumbbell Shape’[J]. Chem. J. Chinese Universities, doi: .

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Synthesis and Characterization of a Novel Azo Compound with ‘Dumbbell Shape’

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