A Photoresponsive Azobenzene-functionalized Covalent Organic Framework †

doi:10.7503/cjcu20200021

Abstract

Abstract:

Covalent organic frameworks(COFs) with high specific surface area, regular structure, and modi-fiable pore channels, are crystalline porous organic polymers and have been widely used in various fields. Azobenzene derivatives with light isomerization characteristics are important stimulus-responsive materials. Herein we report a method of postsynthetic modification for the preparation of photothermal responsive azobenzene-functionalized COF, denoted as JUC-501(JUC=Jilin University China), which based on introducing small azobenzene molecules into the channels of COF(JUC-500). Under ultraviolet irradiation and heating conditions, the COF with azobenzene in the pores will undergo reversible cis-trans isomerization reaction and exhibits excellent reversible capture and release properties for methyl orange(MO).

Key words: Covalent organic frameworks, Azobenzene, Photothermal response, Methyl orange, Reversible capture and release

CLC Number:

O611

TrendMD:

LI Shanshan, ZHAO Wenjuan, LI Hui, FANG Qianrong. A Photoresponsive Azobenzene-functionalized Covalent Organic Framework ^†[J]. Chem. J. Chinese Universities, 2020, 41(6): 1384.

Figures/Tables 7

References 40

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