Synthesis and Characterization of Novel Covalently Linked Fullerene-porphyrin Compouds

Abstract

Abstract: In order to construct a donor-acceptor system with efficient electron transfer, a novel covalently linked fullerene-porphyrin ligand(H₂P-C₆₀) was synthesized by 1,3-dipolar cycloaddition reaction of C₆₀, sarcosine and H₂P-CHO, and it's zinc derivative was prepared by metalation of H₂P-C₆₀ and zinc acetate. The two new fullerene-porphyrin compounds were characterized by means of elemental analysis, IR, electronic spectra, ESI-MS and ¹H NMR.They are also predicted to have good optical and electrical properties.

Key words: Fullerene, Fulleropyrrolidine, Porphyrin, Metal Porphyrin

CLC Number:

O613.71

TrendMD:

YANG Sen-Gen, LIU Jian-Yong, WU Zhen-Yi, TIAN Ling, FAN Su-Hua, ZHAN Meng-Xiong. Synthesis and Characterization of Novel Covalently Linked Fullerene-porphyrin Compouds[J]. Chem. J. Chinese Universities, 2005, 26(7): 1202.

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