Self-assembly of Biphenyl-bridged and Amino Acid-based Macrocycle Compounds

Abstract

Abstract: As part of our efforts aimed at developing molecular receptors and peptide conformational templates, we have conducted a research on design, synthesis, and application of structurally modified cyclopeptides. In this paper, we disigned and synthesized three biphenyl-bridged, amino acid-based macrocycles. The investigation of crystallograghic structures reveals that in the solid state, these macrocycles were assembled into twin-tube, 3D network and chain-like supramolecular structures, respectively, in which the C-H...O hydrogen-bonds play important roles. These findings may be helpful for understanding the role of the C-H...O hydrogen bonding in determining crystal packing, molecular recognition, and the structural stability of biological macromolecules.

Key words: Macrocycle compound, Biphenyl, Amino acid, Self-assembly, C-H...O hydrogen bond

CLC Number:

O625

TrendMD:

GUO Wei, MI Xue-Ling, WANG Jing, HE Jia-Qi, CHENG Jin-Pei. Self-assembly of Biphenyl-bridged and Amino Acid-based Macrocycle Compounds[J]. Chem. J. Chinese Universities, 2005, 26(6): 1086.

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Self-assembly of Biphenyl-bridged and Amino Acid-based Macrocycle Compounds

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