Crystal Structure, Fluorescence Properties and Thermal Stability of Supra-molecule Complex [Eu(C10H9N2O4)(C10H8N2O4)(H2O)3]2·phen·4H2O

Abstract

Abstract: A new superamolecule complex(C₁₀H₁₀N₂O₄, H₃L=2-oxo-propionic acid salicyloyl hydrazone and C₁₂H₈N₂=1,10-phenanthroline phen) was synthesized and its crystal structure of [Eu(C₁₀H₉N₂O₄)·(C₁₀H₈N₂O₄)(H₂O)₃]₂·phen·4H₂O was determined by X-ray diffraction. The crystal belongs to the triclinic system, space group P1 with a=1.378 6(12) nm, b=1.398 8(12) nm, c=1.759 7(16) nm, α=73.977(11)°, β=68.598(12)°, γ=71.224(12)°, V=29.42(4) nm³, Z=2, μ=2.208 mm^-1, D_c=1.746 Mg/m³, F(000)=1 556, R=0.037 7, ωR=0.074 4, GOF=0.916. There are two 9-coordinated structure units in every molecule, in which Eu(Ⅲ) is coordinated by two tridentate C₁₀H₁₀N₂O₄ ligands and three water molecules and both structural units are distorted monocapped square antiprism. There are one free 1,10-phenanthrolines and four water molecules that are connected with 2-oxo-propionic acid salicyloyl hydrazone and water molecule by hydrogen bonds in the crystal cell. The complex formed a supermolecule in space through the hydrogen bonds. The composition of the complex is verified by IR, ¹H NMR and thermal decomposition. The test of luminescence capacity of the complex showed that the complex has a good fluorescence.

Key words: Europium(Ⅲ) complex, 2-Oxo-propionic acid salicyloyl hydrazone, 1,10-Phenanthrolines, Crystal structure, Fluorescence property, Thermal decomposition

CLC Number:

O614

TrendMD:

YANG Rui, HE Shui-Yang, WU Wang-Ting, SHI Qi-Zhen, WANG Da-Qi . Crystal Structure, Fluorescence Properties and Thermal Stability of Supra-molecule Complex [Eu(C₁₀H₉N₂O₄)(C₁₀H₈N₂O₄)(H₂O)₃]₂·phen·4H₂O[J]. Chem. J. Chinese Universities, 2005, 26(3): 401.

References

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Crystal Structure, Fluorescence Properties and Thermal Stability of Supra-molecule Complex [Eu(C₁₀H₉N₂O₄)(C₁₀H₈N₂O₄)(H₂O)₃]₂·phen·4H₂O

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