Highly Effective Sb2O3/Co-ZSM-5 Catalysts for Ethane Ammoxidation

Abstract

Abstract:

The catalytic ammoxidation of ethane with oxygen and ammonia was investigated over a series Sb₂O₃ promoted ion-exchanged Co-ZSM-5 zeolites(Sb₂O₃/Co-ZSM-5).The introduction of appropriate amount of Sb₂O₃can considerably improve the conversion of ethane,suppress the formation of CO_x,and increase the total C₂ selectivity to acetonitrile and ethylene.Among them,the sample with 5% Sb₂O₃loading(in mass fraction) shows a 68.4% ethane conversion at 550 ℃,a 51.6% selectivity to acetonitrile and a 31.7% selectivity to ethylene,and a 35.3% yield of acetonitrile were obtained,which is to our knowledge the highest ever reported for the direct ammoxidation of ethane.

Key words: Sb₂O₃ /Co-ZSM-5; Ethane; Ammoxidation; Acetonitrile, Sb2O₃/Co-ZSM-5, Ethane, Ammoxidation, Acetonitrile

CLC Number:

O643

TrendMD:

PAN Wei-Cheng, LIAN Hong-Lei, JIA Ming-Jun, ZHANG Wen-Xiang, JIANG Da-Zhen. Highly Effective Sb₂O₃/Co-ZSM-5 Catalysts for Ethane Ammoxidation[J]. Chem. J. Chinese Universities, 2005, 26(12): 2348.

[1]	HE Hongrui, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Density-functional Theoretical Study on the Interaction of Indium Oxyhydroxide Clusters with Carbon Dioxide and Methane [J]. Chem. J. Chinese Universities, 2022, 43(8): 20220196.
[2]	TANG Gang, SUN Junjie, ZHANG Dongxin, WU Qiang, ZHANG Hexin, SHEN Haifeng, TAO Yi, LIU Xiuyu. Synthesis of Phosphaphenanthrene-modified Cardanol-based Polyol and Its Performance as Flame Retardant in Rigid Polyurethane Foams [J]. Chem. J. Chinese Universities, 2022, 43(4): 20210847.
[3]	ZHANG Mi, TIAN Yafeng, GAO Keli, HOU Hua, WANG Baoshan. Molecular Dynamics Simulation of the Physicochemical Properties of Trifluoromethanesulfonyl Fluoride Dielectrics [J]. Chem. J. Chinese Universities, 2022, 43(11): 20220424.
[4]	ZHAO Lingyun, HUANG Hanxiong, LUO Duyu, SU Fengchun. Effect of Flexibility of Composites on Performances of Sensors with Micro-structured Inverted Pyramid Arrays [J]. Chem. J. Chinese Universities, 2021, 42(9): 2953.
[5]	LIU Huazheng, PAN Xiaoguang, LI Hua, WAN Renzhong, LIU Xigong. Na₂CO₃-catalyzed 1，6-Conjugate Addition of Trimethylsilyl Azide to δ-CF₃-δ-Aryl-disubstituted Para-Quinone Methides： Efficient Construction of Diarylmethanes Bearing CF₃- and N₃-Substituted Quaternary Stereocenters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2772.
[6]	ZHONG Shengguang, XIA Wensheng, ZHANG Qinghong, WAN Huilin. Theoretical Study on Direct Conversion of CH₄ and CO₂ into Acetic Acid over MCu₂O_x（M = Cu²⁺， Ce⁴⁺， Zr⁴⁺） Clusters [J]. Chem. J. Chinese Universities, 2021, 42(9): 2878.
[7]	HU Chuanchuan, PANG Jingxiang, HE Chuangchuang, LI Wei, SUN Shutao. Sc（OTf）₃ Catalyzed 1，6-Conjugate Allylation of δ-CN p-QMs： Synthesis of Allyl Substituted Diarylacetonitrile Compounds [J]. Chem. J. Chinese Universities, 2021, 42(9): 2805.
[8]	LI Cong, LIU Huanhuan, YANG Guihua, TIAN Zhongjian, YAN Jiaqiang, JI Xingxiang, HAN Wenjia, CHEN Jiachuan. Preparation and Performance Analysis of Extremely High Strength Self-repairing Waterborne Polyurethane Adhesive Based on Oxime-carbamate [J]. Chem. J. Chinese Universities, 2021, 42(8): 2651.
[9]	WANG Aqiang, ZHU Yuzhang, JIN Jian. Preparation of Carboxyl-betaine Polyurethane Hydrogel and Study on Its Underwater Anti-crude-oil-adhesion Property [J]. Chem. J. Chinese Universities, 2021, 42(4): 1246.
[10]	LI Jian, YU Mingming, SUN Yuan, FENG Wenhua, FENG Zhaochi, WU Jianfeng. Effect of Aqueous Solution pH on the Oxidation of Methane to Methanol at Low Temperature [J]. Chem. J. Chinese Universities, 2021, 42(3): 776.
[11]	WU Shuaini, ZHU Pengfei, SHI Huaiqi, LI Na, HU Zhaoxia, CHEN Shouwen. Preparation of CoCr_x/SAPO-34 Catalyst and Its Catalytic Combustion Performance for 1，2-Dichloroethane [J]. Chem. J. Chinese Universities, 2021, 42(12): 3731.
[12]	LU Man,SONG Chunmei,WAN Bo. Thixotropic Behavior of Hydrophobically Modified Ethoxylated Urethane-thickened Waterborne Latex ^† [J]. Chem. J. Chinese Universities, 2020, 41(5): 1108.
[13]	SHEN Wenjie. Molecular-fence Catalysts for Low-temperature Oxidation of Methane to Methanol [J]. Chem. J. Chinese Universities, 2020, 41(3): 375.
[14]	SHENG Yeming,CHENG Bo,LU Xun. Research on Self-healing Polypolyurethane Elastomer Based on Multiple Reversible Action ^† [J]. Chem. J. Chinese Universities, 2020, 41(3): 572.
[15]	WU Hao, WANG Changzhen, QIU Yuan, TIAN Yani, ZHAO Yongxiang. Effect of Steric Confinement Dimension on Metal Site Anti-carbon Deposition Ability of Ni-SiO₂ Catalysts in CH₄-CO₂ Reforming [J]. Chem. J. Chinese Universities, 2020, 41(11): 2488.

Highly Effective Sb₂O₃/Co-ZSM-5 Catalysts for Ethane Ammoxidation

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments