Supramolecular Structure and Properties of Fluorescent Acridine Compound Based on Intermolecular π-π Interaction

Abstract

Abstract: 10-Methyl-benzoacridine(MBA) was synthesized and its crystal structure was characterized by the X-ray crystal diffraction method.The crystals of MBA exhibited monoclinic,space group P2(1)/c,a=0.584 890(1) nm, b=1.486 250(1) nm,c=1.451 62(3) nm,β=98.835(2)°,V=1.247(3) nm³,Z=4.The data of the crystal structure show that one-dimensional infinite columns based on intermolecular(ππ) interactions formed in MBA crystal.The rectangular and wire-like microcrystals of MBA were successfully prepared and characterized by fluorescent microscope.The study of photoluminescence spectra demonstrate that MBA is an organic blue light emitting material.

Key words: Intermolecular π-&pi, interaction, Supraomolecular structure, Organic microcrystal

CLC Number:

O413.57

TrendMD:

SUN Ying-Hui, ZHANG Hui-Dong, YE Kai-Qi, ZHANG Jing-Ying, LI Wei, YANG Bai, WANG Yue . Supramolecular Structure and Properties of Fluorescent Acridine Compound Based on Intermolecular π-π Interaction[J]. Chem. J. Chinese Universities, 2005, 26(10): 1865.

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Supramolecular Structure and Properties of Fluorescent Acridine Compound Based on Intermolecular π-π Interaction

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